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Triisopropylsilane

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Triisopropylsilane Basic information

Product Name:
Triisopropylsilane
Synonyms:
  • Benzenesulfonic acid, 5-[(4-amino-1-naphthalenyl)azo]-2-[2-[4-[(2-hydroxy-1-naphthalenyl)azo]-2-sulfophenyl]ethenyl]-, disodium salt (9CI)
  • Triisopropylsilane
  • tri(propan-2-yl)silicon
  • Sodium 5-[(4-Amino-1-naphthyl)azo]-2-[4-[(2-hydroxy-1-naphthyl)azo]-2-sulfonatostyryl]benzenesulfonate
  • Triisopropylsilane ISO 9001:2015 REACH
  • Sodium 5-((4-aminonaphthalen-1-yl)diazenyl)-2-(4-((2-hydroxynaphthalen-1-yl)diazenyl)-2-sulfonatostyryl)benzenesulfonate
  • 5-((E)-(4-Aminonaphthalen-1-yl)diazenyl)-2-((E)-4-((E)-(2-hydroxynaphthalen-1-yl)diazenyl)-2-sulfonatostyryl)benzenesulfonate (sodium)
CAS:
6459-79-6
MF:
C34H26N5NaO7S2
MW:
703.72
Mol File:
6459-79-6.mol
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Triisopropylsilane Chemical Properties

Boiling point:
169℃
Specific Gravity
0.773
InChIKey
JNXVHUVKJZIDTN-DACWAPEPSA-N
SMILES
N(/C1=CC=C(N)C2=CC=CC=C12)=N/C1C=CC(C=CC2C=CC(/N=N/C3=C(C=CC4=CC=CC=C34)O)=CC=2S(O)(=O)=O)=C(S(O)(=O)=O)C=1.[NaH]
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Triisopropylsilane Usage And Synthesis

Uses

Triisopropylsilane could be used as reductant for variety of reactions; for silylation of heteroarenes and silylation of aldehyde and olefins; and in cross-coupling reactions with olefins, alkynes, alcohols, and oximes.

Preparation

Triisopropylsilane can be prepared by reducing chlorotriisopropylsilane or by reducing triisopropylmethoxysilane using lithium aluminum hydride or DIBAL-H. The reduction of triisopropylmethoxysilane using sodium borohydride also forms triisopropylsilane in 32% yield.

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