ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Phosphine ligand > (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Basic information
- Product Name:
- (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
- Synonyms:
-
- (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
- (R,R)-ME-BPE
- Bisdimethylphospholanoethane
- (+)-1,2-Bis[(2R,5R)-2,5-dimethyphospholano]ethane, Kanata purity
- (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane,98+%(R,R)-Me-BPE
- (+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane,95%
- 1,2-Bis[(2R,5R)-2,5-diMethyl-1-phospholanyl]ethane, 97+%
- (+)-1,2-Bis((2R,5R)-2,5-diMethylphospholano)ethane (R,R)-Me-BPE
- CAS:
- 129648-07-3
- MF:
- C14H28P2
- MW:
- 258.32
- Product Categories:
-
- organophosphine ligand
- Mol File:
- 129648-07-3.mol
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(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Chemical Properties
- Boiling point:
- 64-67 °C 0.06 mm Hg
- alpha
- +263° ±3° (c 1, hexane)
- Density
- 0.940 g/mL at 25 °C
- refractive index
- n20/D 1.534
- form
- liquid
- color
- colorless to pale-yellow
- Sensitive
- Air Sensitive
- CAS DataBase Reference
- 129648-07-3
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MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
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(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Usage And Synthesis
Reactions
The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
Chemical Properties
Clear colorless oily liquid
(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANESupplier
J & K SCIENTIFIC LTD.
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Thermo Fisher Scientific
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(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(129648-07-3)Related Product Information
- Ethyl acetate
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- Ethanol
- (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE
- (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
- (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)trifluoromethanesulfonate
- (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE
- (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
- (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE
- 1,2-BIS((2S,5S)-2,5-DIISOPROPYLPHOSPHOLANO)ETHANE
- (+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE
- (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
- (+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE
- (+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
- (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)trifluoromethanesulfonate
- (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE