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RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL

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RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL Basic information

Product Name:
RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL
Synonyms:
  • 2-(DI-TERT-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL
  • RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL
  • RACEMIC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL
  • rac-2-(Di-t-butylphosphino)-1,1'-binaphthyl,98%
  • racemic-2-Di-t-butylphosphino-1,1'-binaphthyl,98%
  • PHOSPHINE, [1,1''-BINAPHTHALEN]-2-YLBIS(1,1-DIMETHYLETHYL)-
  • 2-(Di-tert-butylphosphino)-1,1'-binaphthyl,98%
  • RaceMic-2-di-tert-butylphosphino-1,1-binaphthyl
CAS:
255836-67-0
MF:
C28H31P
MW:
398.52
Product Categories:
  • Achiral Phosphine
  • Aryl Phosphine
  • Buchwald Ligands Series
  • Buchwald Ligands&Precatalysts
Mol File:
255836-67-0.mol
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RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL Chemical Properties

Melting point:
144-148 °C
Boiling point:
519.5±29.0 °C(Predicted)
form 
crystal
color 
white
InChIKey
QGBQGMHXBSLYLZ-UHFFFAOYSA-N
CAS DataBase Reference
255836-67-0
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26
WGK Germany 
3
TSCA 
No
HS Code 
29029090

MSDS

  • Language:English Provider:ACROS
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RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL Usage And Synthesis

Reaction

  1. Ligand for the Pd-catalyzed formation of oxygen heterocycles.
  2. Ligand for the intermolecular Pd-catalyzed synthesis of aryl ethers.
  3. Ligand for the intramolecular Pd-catalyzed synthesis of aryl ethers.
  4. Ligand for the synthesis of carbazoles by Pd-catalyzed double N-arylation reaction.
  5. Ligand for the Pd-catalyzed cyanation of (hetero)arylchlorides.
  6. Ligand for the Pd-catalyzed intramolecular synthesis of carbazoles via C-H functionalization.

Chemical Properties

White to pale yellow crystalline powder

Uses

2-(Di-tert-butylphosphino)-1,1''-binaphthyl 98% TrixiePhos is a reagent used as ligand in palladium-catalyzed C-O, C-N, and C-C bond forming reactions.

RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYLSupplier

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