ChemicalBook > Product Catalog > Organic Chemistry > Phosphines > (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Basic information
- Product Name:
- (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
- Synonyms:
-
- (R,R)-TROST LIGAND(NAPHTHYL)
- (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),min.94%(R,R)-DACH-NaphthylTrostLigand
- (R,R)-DACH-naphthyl Trost ligand
- (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
- (1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94%
- (1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% (R,R)-DACH-Naphthyl Trost Ligand
- (1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),(R,R)-DACH-Naphthyl Trost Ligand
- N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide)
- CAS:
- 174810-09-4
- MF:
- C52H44N2O2P2
- MW:
- 790.87
- Product Categories:
-
- Chiral Nitrogen
- DACH&Trost Series
- Mol File:
- 174810-09-4.mol
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(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Chemical Properties
- Melting point:
- 224-231 °C
- alpha
- 69o (C=1 IN METHANOL)
- form
- Powder
- pka
- 13.43±0.40(Predicted)
- color
- off-white
- optical activity
- [α]20/D +69.0°, c = 1 in methanol
- InChIKey
- VXFKMKXTPXVEMU-AWSIMMLFSA-N
- CAS DataBase Reference
- 174810-09-4
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Safety Information
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- WGK Germany
- 3
- HS Code
- 2931499090
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(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Usage And Synthesis
Reactions
The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, and fluorides nucleophiles.
Chemical Properties
white to off-white powder
Uses
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)Supplier
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- 021-60702684 18516024827
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(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)(174810-09-4)Related Product Information
- (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
- (1R,2R)-(+)-1,2-Diphenylethylenediamine
- (1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine
- (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
- (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
- (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
- 1,2-Diaminocyclohexane
- N,N'-Dimethyl-1,2-cyclohexanediamine
- TRANS-N,N'-DIACETYLCYCLOHEXANE-1,2-DIAMINE
- Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine
- 2-Diphenylphosphinobenzaldehyde