Cyclopropyl phenyl ketone Chemical Properties

Melting point:

7-9 °C(lit.)

Boiling point:

121-123 °C15 mm Hg(lit.)

Density 

1.058 g/mL at 25 °C(lit.)

vapor density 

5 (vs air)

refractive index 

n20/D 1.553(lit.)

Flash point:

195 °F

storage temp. 

Sealed in dry,2-8°C

form 

clear liquid

color 

Colorless to Light yellow

Water Solubility 

Insoluble in water.

BRN 

1860145

CAS DataBase Reference

3481-02-5(CAS DataBase Reference)

NIST Chemistry Reference

Cyclopropyl phenyl ketone(3481-02-5)

Safety Information

Safety Statements 

23-24/25

WGK Germany 

3

HS Code 

2914390090

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

Cyclopropyl phenyl ketone Usage And Synthesis

Chemical Properties

CLEAR COLOURLESS TO LIGHT YELLOW LIQUID

Uses

Cyclopropyl phenyl ketone is used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It is also used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.

Uses

Cyclopropyl phenyl ketone was used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It was used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl₄-n-Bu₄NI-induced ring opening reaction.

Synthesis Reference(s)

The Journal of Organic Chemistry, 45, p. 2921, 1980 DOI: 10.1021/jo01302a038
Tetrahedron Letters, 16, p. 4389, 1975 DOI: 10.1016/S0040-4039(00)91132-8

Cyclopropyl phenyl ketone(3481-02-5)Related Product Information

• Cyclopropyl methyl ketone
• 4-Methoxyphenylacetone
• N-Methyl-2-pyrrolidone
• 1,3-Diphenylacetone
• DIPHENYLCYCLOPROPENONE
• PHENYL VALERATE
• 3-Pentanone
• Benzophenone
• Cyclohexanone
• Cyclopropyl bromide
• DIMETHYLGLYOXIME DISODIUM SALT
• 3-Methyl-2-butanone
• Dicyclopropane methylamine
• Aminomethylcyclopropane
• PHENYL RESIN
• (4-BROMOPHENYL)(CYCLOPROPYL)METHANONE
• 4-Chlorophenyl cyclopropyl ketone
• Cyclopropyl 4-methoxyphenyl ketone