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Diphenyl-2-pyridylphosphine

Basic information Reaction Safety Supplier Related

Diphenyl-2-pyridylphosphine Basic information

Product Name:
Diphenyl-2-pyridylphosphine
Synonyms:
  • 2-Pyridyldiphenylphosphine
  • Diphenyl(2-pyridinyl)phosphine
  • 2-(diphenylphosphanyl)pyridine
  • 2-Diphenylphosphinopyridine, min. 97%
  • DPPPY/DIPHENYL-2-PYRIDYL
  • Diphenyl-2-pyridylphosphine 97%
  • DIPHENYL-2-PYRIDYLPHOSPHINE
  • 2-(DIPHENYLPHOSPHINO)PYRIDINE
CAS:
37943-90-1
MF:
C17H14NP
MW:
263.27
EINECS:
629-049-1
Product Categories:
  • Heterocycles
  • Intermediates & Fine Chemicals
  • Phosphines
  • Aromatics
  • Chelating Agents & Ligands
  • Pharmaceuticals
  • Mitsunobu Reaction
  • Phosphine Ligands
  • Phosphines (Mitsunobu Reaction)
  • Synthetic Organic Chemistry
  • Catalysis and Inorganic Chemistry
  • Phosphine Ligands
  • Phosphorus Compounds
  • Achiral Phosphine
  • Aryl Phosphine
Mol File:
37943-90-1.mol
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Diphenyl-2-pyridylphosphine Chemical Properties

Melting point:
82-84 °C (dec.) (lit.)
Boiling point:
163 °C(Press: 0.05 Torr)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Soluble in toluene. (almost transparency)
pka
2.37±0.12(Predicted)
form 
Crystalline Powder
color 
White to yellow to tan
InChIKey
SVABQOITNJTVNJ-UHFFFAOYSA-N
CAS DataBase Reference
37943-90-1(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29333990

MSDS

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Diphenyl-2-pyridylphosphine Usage And Synthesis

Reaction

Ligand for the palladium-catalyzed distannylation of ortho-quinodimethanes
Ligand for the palladium-catalyzed disilylation of o-quinodimethanes to synthesize 9- and 10-membered disilacarbocycles
Ligand for the palladium-catalyzed alkoxycarbonylation of allenes

Chemical Properties

Yellow to orange crystalline powder

Uses

suzuki reaction

Uses

Ligand for metal-catalyzed carbonylations, hydration, dehydrogenative coupling, carbostannylation, distannylation, and silylation; reagent for Mitsunobu reaction.

Uses

Diphenyl-2-pyridylphosphine is an organophosphorous compound that is a widely used mono-pyridylphosphine ligand in transition metal complexes for catalysis.

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