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TRIS(PENTAFLUOROPHENYL)BORANE

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TRIS(PENTAFLUOROPHENYL)BORANE Basic information

Product Name:
TRIS(PENTAFLUOROPHENYL)BORANE
Synonyms:
  • PERFLUOROTRIPHENYLBORANE
  • TRIS(PENTAFLUOROPHENYL)BORANE
  • TRIS(PENTAFLUOROPHENYL)BORON
  • Tris(2,3,4,5,6-pentafluorophenyl)borane
  • TRIS(PENTAFLUOROPHENYL)BORANE SOLUTION, ~3% IN ISOPAR
  • TRIS(PENTAFLUOROPHENYL)BORON, 97+%
  • Tris(Pentafluorophenyl)Borate
  • Tris(pentafluorophenyl)boron,min.97%
CAS:
1109-15-5
MF:
C18BF15
MW:
511.98
EINECS:
000-000-0
Product Categories:
  • organoboron compound
  • BoronAlphabetic
  • B (Classes of Boron Compounds)
  • Precursors by Metal
  • TP - TZ
  • Vapor Deposition Precursors
  • Boranes
Mol File:
1109-15-5.mol
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TRIS(PENTAFLUOROPHENYL)BORANE Chemical Properties

Melting point:
126-131 °C (lit.)
Boiling point:
327.3±42.0 °C(Predicted)
Density 
0.73 g/mL at 20 °C
refractive index 
n20/D 1.41
Flash point:
7 °C
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
solubility 
Soluble in hexane, chloroform, dichloromethane, toluene, and polar solvents.
form 
Powder
Specific Gravity
1.7
color 
White to light yellow-beige
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
λmax
306nm(Toluene)(lit.)
Merck 
14,9755
BRN 
2931347
InChIKey
OBAJXDYVZBHCGT-UHFFFAOYSA-N
CAS DataBase Reference
1109-15-5(CAS DataBase Reference)
EPA Substance Registry System
Borane, tris(2,3,4,5,6-pentafluorophenyl)- (1109-15-5)
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Safety Information

Hazard Codes 
Xi,T,N,Xn,F
Risk Statements 
36/37/38-25-67-65-50/53-38-11
Safety Statements 
60-61-62-45-37/39-26-36
RIDADR 
UN 1268 3/PG 2
WGK Germany 
3
TSCA 
No
HazardClass 
6.1
PackingGroup 
III
HS Code 
29039990

MSDS

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TRIS(PENTAFLUOROPHENYL)BORANE Usage And Synthesis

Uses

Tris(pentafluorophenyl)borane (CAS# 1109-15-5) is a useful research chemical, used as a catalyst in the metal-free catalytic reductive cleavage of enol ethers via proposed mechanism of tandem hydrosilylation and silicon-​assisted β-​elimination. Tris(pentafluorophenyl)borane also appears as an ancillary ligand in luminescent isocyano Rh(I) complexes.

Chemical Properties

white powder

Uses

Tris(pentafluorophenyl)borane is used as an excellent activator component in homogeneous Ziegler-Natta chemistry. It is also used as a catalyst for reductions, alkylations, hydrometallation reactions and catalyzed aldol-type reactions. It is a useful Lewis acid and catalyzes hydrosilylation of aldehydes. Further, it is used in olefin polymerization catalysis. It serves as a reagent in the preparation of organometallic complexes. In addition to this, it is useful as polymerization catalysts and used to study the heterolytic cleavage of dihydrogen in associated with tri-tert-butylphosphine.

Uses

Catalyst in organic transformations; cocatalyst with group IV metallocene alkyls in olefin polymerization.

General Description

B(C6F5)3 is a Lewis acid, stronger than the inorganic parent molecule BF3. In contrast to the prominent Lewis acids, the pentafluorides of the heavier elements of group 15, B(C6F5)3 has no oxidizing properties. B(C6F5)3 forms adducts with neutral and weaker Lewis bases. B(C6F5)3 has the capability to easily accept anionic ligands bonded to metals.

TRIS(PENTAFLUOROPHENYL)BORANE Preparation Products And Raw materials

Raw materials

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