Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Basic information
- Product Name:
- Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
- Synonyms:
-
- Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
- (R)-Ru(OAc)2(BINAP)
- Dimethylammonium dichlorotri(chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((R)-segphos)}2(Cl)3]
- (R)-[(RuCl(SEGPHOS))2(μ-Cl)3][NH2Me2]
- (R)-[(RUCL(SEGPHOS)2(Μ-CL)3[NH2ME2]
- [NH2Me2][(RuCl((R)-segphos(regR)))2(mu-Cl)3]
- (R)-[(RuCl(SEGPHOS(R)))2(mu-Cl)3][NH2Me2]
- [NH2ME2][(RUCL((R)-SEGPHOS))2(Μ-CL)3]
- CAS:
- 346457-41-8
- MF:
- 2C38H28O4P2.C2H7N.Cl.Cl3Ru2.ClH
- MW:
- 1646.66
- Product Categories:
-
- Ru
- Mol File:
- 346457-41-8.mol
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Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Chemical Properties
- Melting point:
- >100°C
- storage temp.
- 2-8°C
- Water Solubility
- Insoluble in water
- form
- Powder
- color
- light brown
- Sensitive
- air sensitive
- CAS DataBase Reference
- 346457-41-8
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Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Usage And Synthesis
Uses
Takasago Ligands and Complexes for Asymmetric Reactions
General Description
(R)-[(RuCl(SEGPHOS?))2(μ-Cl)3][NH2Me2] is a ruthenium-based catalyst generally used in the asymmetric hydrogenation reactions of ketones. SEGPHOS?, the chiral ligand and its ruthenium-based catalysts are developed and commercialized by Takasago International Corporation.
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)Supplier
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Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)(346457-41-8)Related Product Information
- Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl
- Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl
- Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((S)-dm-segphos)]Cl
- Chloro{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((R)-dtbm-segphos)]Cl
- Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl
- Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II)chloride[RuCl (p-cymene)((S)-segphos)]Cl
- Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3]
- Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3]
- Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
- Tris(triphenylphosphine)ruthenium(II) chloride
- (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS
- DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
- CHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
- Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
- DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
- RUTHENIUM(III) CHLORIDE TRIHYDRATE
- Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-5,5μ-bis[di(3,5-xylyl)phosphino]-4,4μ-bi-1,3-benzodioxole]diruthenate(II)