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Azocyclotin

Basic information Safety Supplier Related

Azocyclotin Basic information

Product Name:
Azocyclotin
Synonyms:
  • AZOCYCLOTIN PESTANAL (1-(TRICYCLO- HEXYL
  • AZOCYCLOTIN, 250MG, NEAT
  • Tricyclotin
  • 1-(tricyclohexylstannyl)-1H-1,2,4-triazole azocyclotin
  • 1H-1,2,4-Triazole, 1-(tricyclohexylstannyl)-
  • azocyclotin (bsi,iso,esa)
  • AZOCYCLOTIN STANDARD
  • Clermait
CAS:
41083-11-8
MF:
C20H35N3Sn
MW:
436.22
EINECS:
255-209-1
Product Categories:
  • INSECTICIDE
  • A-BPesticides&Metabolites
  • AR to AZ
  • A
  • AcaricidesAlphabetic
  • Alpha sort
  • Pesticides
  • Pesticides&Metabolites
Mol File:
41083-11-8.mol
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Azocyclotin Chemical Properties

Melting point:
210℃
Boiling point:
487.4±28.0 °C(Predicted)
vapor pressure 
2×10-11 Pa (20 °C, est.)
storage temp. 
0-6°C
solubility 
Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
pka
5.36 (weak base)
Water Solubility 
0.12 mg l-1 (20 °C)
BRN 
621636
CAS DataBase Reference
41083-11-8(CAS DataBase Reference)
NIST Chemistry Reference
1H-1,2,4-triazole, 1-(tricyclohexylstannyl)-(41083-11-8)
EPA Substance Registry System
Azocyclotin (41083-11-8)
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Safety Information

Hazard Codes 
T+;N,N,T+
Risk Statements 
25-26-37/38-41-50/53
Safety Statements 
26-28-36/37/39-38-45-60-61
RIDADR 
UN 2786
WGK Germany 
3
RTECS 
WH8637700
HazardClass 
6.1(a)
PackingGroup 
I
Hazardous Substances Data
41083-11-8(Hazardous Substances Data)

MSDS

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Azocyclotin Usage And Synthesis

Uses

Azocyclotin is an organotin aracacide used in the control of mites. Azocyclotin showed weak antifeedant activity against other insects such as Spodoptera littoralis.

Uses

Azocyclotin is used to control all motile stages of spider mites on fruit, vines, hops, cotton, vegetables and ornamentals.

Definition

ChEBI: A member of the class of triazoles that is 1,2,4-triazole substituted at position 1 by a tricyclohexylstannyl group.

Metabolic pathway

The sedimentation of particles coated with the pesticide is relatively fast. Shortly after application of 14C-azocyclotin, distribution, solubilizing, and metabolism in fresh water microcosms begin, and azocyclotin is quickly hydrolyzed to cyhexatin (tricyclohexyltin hydroxide) by splitting of the triazole residue, and, according to the solubility of cyhexatin, cyhexatin is mainly absorbed to sediment and the layer of biota in direct contact with the sediment and further undergoes successive metabolism to result in dicyclohexyltin oxide and cyclohexyltin acid.

Degradation

Azocyclotin undergoes hydrolysis with DT50 values (22 °C) of 96 hours at pH 4,81 hours at pH 7 and 8 hours at pH 9 (I'M).

Azocyclotin Preparation Products And Raw materials

Raw materials

Preparation Products

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