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trans-2-Hexenoic acid

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trans-2-Hexenoic acid Basic information

Product Name:
trans-2-Hexenoic acid
Synonyms:
  • T2 HEXENOIC ACID
  • TIMTEC-BB SBB009088
  • ISOHYDROSORBIC ACID
  • HEX-2(TRANS)-ENOIC ACID
  • FEMA NUMBER 3169
  • FEMA 3169
  • BETA-PROPYLACRYLIC ACID
  • 2-HEXENOIC ACID
CAS:
13419-69-7
MF:
C6H10O2
MW:
114.14
EINECS:
236-528-5
Product Categories:
  • C6
  • Carbonyl Compounds
  • Alphabetical Listings
  • Flavors and Fragrances
  • G-H
  • Carboxylic Acids
Mol File:
13419-69-7.mol
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trans-2-Hexenoic acid Chemical Properties

Melting point:
33-35 °C (lit.)
Boiling point:
217 °C (lit.)
Density 
0.965 g/mL at 25 °C (lit.)
vapor density 
>1 (vs air)
refractive index 
n20/D 1.438(lit.)
FEMA 
3169 | TRANS-2-HEXENOIC ACID
Flash point:
>230 °F
storage temp. 
2-8°C
Water Solubility 
Insoluble in water
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
powder to lump to clear liquid
pka
pK1:4.74 (25°C)
color 
White or Colorless to Light yellow
Specific Gravity
0.965
Odor
at 1.00 % in propylene glycol. powerful fruity sweet warm herbal
Odor Type
fruity
JECFA Number
1361
BRN 
1720443
InChIKey
NIONDZDPPYHYKY-SNAWJCMRSA-N
LogP
1.87
CAS DataBase Reference
13419-69-7(CAS DataBase Reference)
NIST Chemistry Reference
2-Hexenoic acid, (E)-(13419-69-7)
EPA Substance Registry System
2-Hexenoic acid, (2E)- (13419-69-7)
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Safety Information

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45-25
RIDADR 
UN 2829 8/PG 3
WGK Germany 
3
TSCA 
T
HazardClass 
8
PackingGroup 
III
HS Code 
29161900

MSDS

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trans-2-Hexenoic acid Usage And Synthesis

Description

trans-2-Hexenoic acid has a pleasant fatty characteristic and is long-lasting. This substance may be synthesized by condensation of butyraldehyde with malonic acid.

Chemical Properties

trans-2-Hexenoic acid has a pleasant, fatty, characteristic, long-lasting odor.

Chemical Properties

white crystalline low melting solid

Occurrence

Reported found in Japanese peppermint oil, apple, banana, bilberry, guava, pork fat, white wine, tea, starfruit, loquat and loganberry.

Uses

(2E)-2-Hexenoic Acid is used in the synthesis of antitumor dehydroepiandrosteronederivatives. Also used in the synthesis of phosphatase 1B inhibitors.

Preparation

By condensation of butyraldehyde with malonic acid

Definition

ChEBI: The (E)-stereoisomer of hexenoic acid.

trans-2-Hexenoic acid Preparation Products And Raw materials

Raw materials

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