Basic information Safety Supplier Related
ChemicalBook >  Product Catalog >  Pharmaceutical intermediates >  Heterocyclic compound >  1H-Benzotriazole-5-carboxylic acid

1H-Benzotriazole-5-carboxylic acid

Basic information Safety Supplier Related

1H-Benzotriazole-5-carboxylic acid Basic information

Product Name:
1H-Benzotriazole-5-carboxylic acid
Synonyms:
  • 5-CARBOXYL BENZOTRIAZOLE
  • 5-CARBOXYBENZOTRIAZOLE
  • 1-H-BENZOTRIAZOLECARBOXYLIC ACID
  • 1H-BENZOTRIAZOLE-5-CARBOXYLIC ACID
  • BUTTPARK 98\57-27
  • COBRATEC(R) CBT
  • OTAVA-BB BB7117850639
  • ZERENEX E/6026513
CAS:
60932-58-3
MF:
C7H5N3O2
MW:
163.13
EINECS:
262-527-4
Mol File:
60932-58-3.mol
More
Less

1H-Benzotriazole-5-carboxylic acid Chemical Properties

InChI
InChI=1S/C7H5N3O2/c11-7(12)4-1-2-5-6(3-4)9-10-8-5/h1-3H,(H,11,12)(H,8,9,10)
InChIKey
GUOVBFFLXKJFEE-UHFFFAOYSA-N
SMILES
N1C2=CC=C(C(O)=O)C=C2N=N1
CAS DataBase Reference
60932-58-3(CAS DataBase Reference)
EPA Substance Registry System
1H-Benzotriazolecarboxylic acid (60932-58-3)
More
Less

Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3

MSDS

More
Less

1H-Benzotriazole-5-carboxylic acid Usage And Synthesis

Uses

Used as an intermediate for organic synthesis.

Synthesis

1H-Benzotriazole-5-carboxylic acid was formed of carboxytriazole (3.91 g, 24 mmol), 4-dimethylaminopyridine (0.32 g, 2.6 mmol), dimethylformamide (58 g) andatert-butyl methyl ether (46 g) solution of ZTETRAOL 2000s produced by the SOLVAY SOLEXIS company (Mn of 1730 for Rf(F)=-CF2O (CF2CF2O)m(CF2O)nCF2-) (13.26 g, 6.0 mmol) which had four terminal hydroxyl groups, as a perfluoropolyether were added sequentially to a three-necked flask which had been fitted with a nitrogen bubbling tube and a stirrer. 1-Ethy3- (3-dimethylaminopropyl)carboxylmide hydrochloride (4.60 g, 24 mmol) was added at room temperature and stirred for 24 hours at 50°C. Water (60 g) and methyl isobutyl ketone (60 g) were added to the reaction solution and the liquid was partitioned. The organic layer was washed two or three times with 1% hydrochloric acid aqueous solution (50 g) and saturated salt water (50 g) and then dried with anhydrous sodium sulphate and concentrated and 1H-Benzotriazole-5-carboxylic acid was obtained. Yield (10.1 g).

1H-Benzotriazole-5-carboxylic acidSupplier

WISPO?Advanced?Materials?(Suzhou) Co., Ltd. Gold
Tel
18112619888
Email
service@wispo.com.cn
Zibo Biopolar Rongchuang Pharmaceutical Co. Ltd. Gold
Tel
0533-6092686 13371592196
Email
ddliu@bio-polar.cn
NEW SANITARY INTERNATIONAL LIMITED Gold
Tel
+86-13611854774 15502117565
Email
essenoichemical@outlook.com
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Email
3bsc@sina.com
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Email
3007715519@qq.com