Basic information Safety Supplier Related
ChemicalBook >  Product Catalog >  Organic Chemistry >  Organometallic compounds >  Organotin >  TETRAVINYLTIN

TETRAVINYLTIN

Basic information Safety Supplier Related

TETRAVINYLTIN Basic information

Product Name:
TETRAVINYLTIN
Synonyms:
  • TETRAVINYLTIN
  • TETRAVINYLTIN(IV)
  • TIN TETRAVINYL
  • Sn(CH=CH2)4
  • Stannane, tetravinyl-
  • Stannane,tetraethenyl-
  • Stannane,tetravinyl-
  • Tetravinylstannane
CAS:
1112-56-7
MF:
C8H12Sn
MW:
226.89
EINECS:
214-193-6
Product Categories:
  • Organometallic Reagents
  • Organotin
  • OrganotinsVapor Deposition Precursors
  • Precursors by Metal
  • Tin
Mol File:
1112-56-7.mol
More
Less

TETRAVINYLTIN Chemical Properties

Boiling point:
160-163 °C (lit.)
Density 
1.246 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.501(lit.)
Flash point:
105 °F
storage temp. 
Flammables area
solubility 
sol common organic solvents; insol H2O
form 
clear liquid
color 
Colorless to Almost colorless
Specific Gravity
1.257
Hydrolytic Sensitivity
1: no significant reaction with aqueous systems
BRN 
3535492
CAS DataBase Reference
1112-56-7(CAS DataBase Reference)
NIST Chemistry Reference
Stannane, tetraethenyl-(1112-56-7)
EPA Substance Registry System
Stannane, tetraethenyl- (1112-56-7)
More
Less

Safety Information

Hazard Codes 
T
Risk Statements 
10-23/24/25
Safety Statements 
36/37/39-45
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
TSCA 
No
HazardClass 
6.1(a)
PackingGroup 
II
HS Code 
29319090

MSDS

More
Less

TETRAVINYLTIN Usage And Synthesis

Chemical Properties

clear colorless to very light yellow liquid

Uses

Tetravinyltin is used as a vinyllithium precursor; vinyl nucleophile source for Stille coupling.

Synthesis Reference(s)

1.Gassman, P. G.; Valcho, J. J.; Proehl, G. S.; Cooper, C. F. JACS 1980, 102, 6519.

reaction suitability

core: tin

Synthesis

Tetravinyltin is synthesized by the reaction of Vinylmagnesium Bromide with Tin(IV) Chloride in THF.1

Purification Methods

Commercial tetravinyltin is commonly used without further purification. Large quantities are purified by fractional distillation. Smaller amounts may be filtered through a plug of silica.

Precautions

Tetravinyltin is toxic and should only be used in a well ventilated hood. All glassware should be rinsed in a KOH/EtOH bath during cleaning.

TETRAVINYLTINSupplier

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Email
jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Email
market03@meryer.com
INTATRADE GmbH
Tel
+49 3493/605464
Email
sales@intatrade.de
Energy Chemical
Tel
021-021-58432009 400-005-6266
Email
sales8178@energy-chemical.com
Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Email
sales@chemreagents.com
More
Less

TETRAVINYLTIN(1112-56-7)Related Product Information