ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organotin > TETRAVINYLTIN
TETRAVINYLTIN
TETRAVINYLTIN Basic information
- Product Name:
- TETRAVINYLTIN
- Synonyms:
-
- TETRAVINYLTIN
- TETRAVINYLTIN(IV)
- TIN TETRAVINYL
- Sn(CH=CH2)4
- Stannane, tetravinyl-
- Stannane,tetraethenyl-
- Stannane,tetravinyl-
- Tetravinylstannane
- CAS:
- 1112-56-7
- MF:
- C8H12Sn
- MW:
- 226.89
- EINECS:
- 214-193-6
- Product Categories:
-
- Organometallic Reagents
- Organotin
- OrganotinsVapor Deposition Precursors
- Precursors by Metal
- Tin
- Mol File:
- 1112-56-7.mol
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TETRAVINYLTIN Chemical Properties
- Boiling point:
- 160-163 °C (lit.)
- Density
- 1.246 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.501(lit.)
- Flash point:
- 105 °F
- storage temp.
- Flammables area
- solubility
- sol common organic solvents; insol H2O
- form
- clear liquid
- color
- Colorless to Almost colorless
- Specific Gravity
- 1.257
- Hydrolytic Sensitivity
- 1: no significant reaction with aqueous systems
- BRN
- 3535492
- CAS DataBase Reference
- 1112-56-7(CAS DataBase Reference)
- NIST Chemistry Reference
- Stannane, tetraethenyl-(1112-56-7)
- EPA Substance Registry System
- Stannane, tetraethenyl- (1112-56-7)
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Safety Information
- Hazard Codes
- T
- Risk Statements
- 10-23/24/25
- Safety Statements
- 36/37/39-45
- RIDADR
- UN 1993 3/PG 3
- WGK Germany
- 3
- TSCA
- No
- HazardClass
- 6.1(a)
- PackingGroup
- II
- HS Code
- 29319090
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
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TETRAVINYLTIN Usage And Synthesis
Chemical Properties
clear colorless to very light yellow liquid
Uses
Tetravinyltin is used as a vinyllithium precursor; vinyl nucleophile source for Stille coupling.
Synthesis Reference(s)
1.Gassman, P. G.; Valcho, J. J.; Proehl, G. S.; Cooper, C. F. JACS 1980, 102, 6519.
reaction suitability
core: tin
Synthesis
Tetravinyltin is synthesized by the reaction of Vinylmagnesium Bromide with Tin(IV) Chloride in THF.1
Purification Methods
Commercial tetravinyltin is commonly used without further purification. Large quantities are purified by fractional distillation. Smaller amounts may be filtered through a plug of silica.
Precautions
Tetravinyltin is toxic and should only be used in a well ventilated hood. All glassware should be rinsed in a KOH/EtOH bath during cleaning.
TETRAVINYLTINSupplier
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 021-61259108 18621169109
- market03@meryer.com
INTATRADE GmbH
- Tel
- +49 3493/605464
- sales@intatrade.de
Energy Chemical
- Tel
- 021-021-58432009 400-005-6266
- sales8178@energy-chemical.com
Pure Chemistry Scientific Inc.
- Tel
- 001-857-928-2050 or 1-888-588-9418
- sales@chemreagents.com