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Ethyl 4-bromobenzoate

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Ethyl 4-bromobenzoate Basic information

Product Name:
Ethyl 4-bromobenzoate
Synonyms:
  • ETHYL P-BROMOBENZOATE
  • ETHYL 4-BROMOBENZOATE
  • 4-BROMOBENZOIC ACID ETHYL ESTER
  • RARECHEM AL BI 0075
  • 4-bromo-benzoicaciethylester
  • Benzoic acid, p-bromo-, ethyl ester
  • p-(Ethoxycarbonyl)phenyl bromide
  • Ethyl 4-BroMobenzoate, 98.0%(GC)
CAS:
5798-75-4
MF:
C9H9BrO2
MW:
229.07
EINECS:
227-347-2
Product Categories:
  • Aromatic Esters
  • Acids & Esters
  • Bromine Compounds
  • C8 to C9
  • Carbonyl Compounds
  • Esters
Mol File:
5798-75-4.mol
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Ethyl 4-bromobenzoate Chemical Properties

Melting point:
18 °C
Boiling point:
131 °C/14 mmHg (lit.)
Density 
1.403 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.544(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
form 
clear liquid
color 
Colorless to Light yellow to Light orange
Specific Gravity
1.403
Water Solubility 
Insoluble
Merck 
14,1408
BRN 
1867129
InChIKey
XZIAFENWXIQIKR-UHFFFAOYSA-N
CAS DataBase Reference
5798-75-4(CAS DataBase Reference)
NIST Chemistry Reference
Benzoic acid, 4-bromo-, ethyl ester(5798-75-4)
EPA Substance Registry System
Benzoic acid, 4-bromo-, ethyl ester (5798-75-4)
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Safety Information

Hazard Codes 
Xi,N
Risk Statements 
36/37/38-51/53
Safety Statements 
24/25-61
RIDADR 
UN 3082 9 / PGIII
WGK Germany 
3
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29163990

MSDS

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Ethyl 4-bromobenzoate Usage And Synthesis

Chemical Properties

clear colorless to yellow liquid

Uses

Ethyl 4-bromobenzoate undergoes reduction with potassium diisobutyl-t-butoxyaluminum hydride (PDBBA) at 0°C to yield aldehydes. Reaction of ethyl 4-bromobenzoate and substituted benzyl chloride with zinc dust and a Pd catalyst is reported.

Synthesis Reference(s)

Synthetic Communications, 22, p. 1851, 1992 DOI: 10.1080/00397919208021316
Synthesis, p. 191, 1983

General Description

Ethyl 4-bromobenzoate is an ester having electron-withdrawing substituent. It undergoes reduction with potassium diisobutyl-t-butoxyaluminum hydride (PDBBA) at 0°C to yield aldehydes. Reaction of ethyl 4-bromobenzoate and substituted benzyl chloride with zinc dust and a Pd catalyst is reported.

Ethyl 4-bromobenzoate Preparation Products And Raw materials

Preparation Products

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