ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organic palladium > Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Basic information
- Product Name:
- Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
- Synonyms:
-
- BIS[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]-PALLADIUM
- BIS[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]PALLADIUM(0)
- BIS(DIPHOS)PALLADIUM(0)
- PD(DIPHOS)2
- bis(ethylenebis(diphenylphosphine))palladium
- Bisbisdiphenylphosphinoethanepalladium
- Bis[1,2-bis(diphenylphosphino)ethane]palladium(0),98%
- Pd(dppe)2
- CAS:
- 31277-98-2
- MF:
- C52H48P4Pd
- MW:
- 903.25
- EINECS:
- 625-554-6
- Product Categories:
-
- Pd
- Pyrimidines
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Homogeneous Catalysts
- metal-phosphine complexes
- Metal Complexes
- Pd (Palladium) Compounds
- Synthetic Organic Chemistry
- Transition Metal Compounds
- Mol File:
- 31277-98-2.mol
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Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Chemical Properties
- Melting point:
- 219-225 °C
- storage temp.
- -20°C
- solubility
- sol nonprotic solvents
- form
- Powder
- color
- orange
- Water Solubility
- insoluble
- Sensitive
- Air Sensitive
- InChI
- InChI=1S/2C26H24P2.Pd/c2*1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;/h2*1-20H,21-22H2;
- InChIKey
- UTBLWXFSGOYWOH-UHFFFAOYSA-R
- SMILES
- P(CCP(C1=CC=CC=C1)C1=CC=CC=C1)(C1C=CC=CC=1)C1=CC=CC=C1.P(CCP(C1=CC=CC=C1)C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Pd]
- CAS DataBase Reference
- 31277-98-2
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Safety Information
- Hazard Codes
- Xn,Xi
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 36-37/39-26
- RIDADR
- 1479
- WGK Germany
- 3
- HazardClass
- 5.1
- PackingGroup
- III
- HS Code
- 28439000
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
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Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Usage And Synthesis
Chemical Properties
yellow to orange crystalline powder
Uses
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) is a homogeneous catalyst most widely used in allylic substitution reactions; good catalyst for bulky substrates; slowly dissociating ligand that gives good stereoselectivity.
storage
air and light sensitive. If stored under nitrogen or argon it is stable for about one month. Avoid inhalation. Use in a fume hood.
Purification Methods
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) can be recrystallized from benzene-ethanol or ethanol.
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)Supplier
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 021-61259108 18621169109
- market03@meryer.com
Alfa Aesar
- Tel
- 400-6106006
- saleschina@alfa-asia.com
TCI (Shanghai) Development Co., Ltd.
- Tel
- 021-67121386
- Sales-CN@TCIchemicals.com
ShangHai DEMO Chemical Co.,Ltd
- Tel
- 400-021-7337 2355568890
- sales@demochem.com
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Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)(31277-98-2)Related Product Information
- N-(Carboxymethyl)-N-(phosphonomethyl)-glycine
- Hexafluoroethane
- Chlorodiphenylphosphine
- ETHANE
- Diphenylphosphine
- Palladium
- tert-Butylchlorodiphenylsilane
- Chloro(1,5-cyclooctadiene)iridium(I) dimer
- Bis(dibenzylideneacetone)palladium
- Bis(benzonitrile)palladium chloride
- Bis(triphenylphosphinepalladium) acetate
- Bis(tricyclohexylphosphine)palladium(II) Dichloride
- BIS(1,5-CYCLOOCTADIENE)IRIDIUM (I) TETRAFLUOROBORATE
- BIS(1 5-CYCLOOCTADIENE)RHODIUM(I)
- Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
- Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
- 1,2-BIS(PHOSPHINO)ETHANE
- 1,2-Bis(diphenylphosphino)ethane