ChemicalBook > Product Catalog > Natural Products > Alkaloids > 6β-Acetoxy-15,23-dideoxy-19,23-epoxyajaconine
6β-Acetoxy-15,23-dideoxy-19,23-epoxyajaconine
6β-Acetoxy-15,23-dideoxy-19,23-epoxyajaconine Basic information
- Product Name:
- 6β-Acetoxy-15,23-dideoxy-19,23-epoxyajaconine
- Synonyms:
-
- 6β-Acetoxy-15,23-dideoxy-19,23-epoxyajaconine
- Spiradine F
- 12aH,14H-3,14a-Ethano-14,4b,8-ethanylylidene-1H,5H-[2]benzopyrano[4,3-g]oxazolo[3,2-a]azocin-17-ol, decahydro-8-methyl-2-methylene-, 17-acetate, (3S,4aR,4bR,8R,8aS,12aR,14S,14aR,17S,18R)-
- CAS:
- 21040-64-2
- MF:
- C24H33NO4
- MW:
- 399.53
- Mol File:
- 21040-64-2.mol
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6β-Acetoxy-15,23-dideoxy-19,23-epoxyajaconine Chemical Properties
- Boiling point:
- 510.5±50.0 °C(Predicted)
- Density
- 1.27±0.1 g/cm3(Predicted)
- pka
- 3.79±0.60(Predicted)
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6β-Acetoxy-15,23-dideoxy-19,23-epoxyajaconine Usage And Synthesis
Description
This alkaloid from Spiraea japonica L. fil. has been obtained as the crystalline hydrochloride, m.p. l14-7°C. Chemical evidence has shown it to be acetyl_x0002_spiradine G. Oxidation with chromic acid in pyridine yields a hydroxy-Iactam in which the hydroxyl and lactam groups are formed by oxidative cleavage of an intermediate alkanolamine ether.
References
Toda, Hirata., Tetrahedron Lett., 5565 (1968)
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