LITHIUM TRIMETHYLSILANOLATE Chemical Properties

Boiling point:

40 °C

Density 

1.278 g/mL at 25 °C

vapor pressure 

24.12 psi ( 55 °C)

Flash point:

145 °F

form 

solid

Specific Gravity

0.876

Hydrolytic Sensitivity

7: reacts slowly with moisture/water

BRN 

3686900

InChI

1S/C3H9OSi.Li/c1-5(2,3)4;/h1-3H3;/q-1;+1

InChIKey

OXOZHAWWRPCVGL-UHFFFAOYSA-N

SMILES

[Li+].C[Si](C)(C)[O-]

Safety Information

Hazard Codes 

C,T

Risk Statements 

34-40-23/24/25

Safety Statements 

26-28-36/37/39-45-27-16

RIDADR 

UN 3267 8/PG 2

WGK Germany 

3

RTECS 

VV7175000

F 

10-21

TSCA 

No

HazardClass 

8

PackingGroup 

III

HS Code 

29310099

Storage Class

8A - Combustible corrosive hazardous materials

Hazard Classifications

Eye Dam. 1
Skin Corr. 1B

MSDS

• Language:English Provider:SigmaAldrich

LITHIUM TRIMETHYLSILANOLATE Usage And Synthesis

Uses

• Enhanced process and composition control for atomic layer deposition with lithium trimethylsilanolate: This study reports on the novel lithium precursor, lithium trimethylsilanolate (LiTMSO), for atomic layer deposition, comparing it with other lithium precursors for improved process and composition control (Ruud et al., 2017).


• Trimethylsiloxy based metal complexes as electrolyte additives for high voltage application in lithium ion cells: The paper discusses the synthesis of lithium trimethylsilanolate and its use as an additive to enhance the performance of high voltage lithium ion cells (Imholt et al., 2017).


• Application of trimethylsilanolate alkali salts in organic synthesis: This review covers various applications of lithium trimethylsilanolate in organic synthesis, highlighting its role in different reactions (Bürglová and Hlaváč, 2018).

Purification Methods

Wash it with Et2O and pet ether. It sublimes at 180o/1mm as fine transparent needles. [Tatlock & Rochnow J Org Chem 17 1555 1952, Beilstein 4 IV 3992.] Suspected CARCINOGEN.

LITHIUM TRIMETHYLSILANOLATE(2004-14-0)Related Product Information

• 2,2-DiMethyl-3-oxo-pyrrolidine-1-carboxylicacidethylester
• hydroxytrimethylsilane
• Potassium trimethylsilanolate
• Lithium
• Lithium silicon
• LITHIUM TRIMETHYLSILANOLATE