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1-(TRIISOPROPYLSILYL)PYRROLE

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1-(TRIISOPROPYLSILYL)PYRROLE Basic information

Product Name:
1-(TRIISOPROPYLSILYL)PYRROLE
Synonyms:
  • 1-TRIISOPROPYLSILANYL-1H-PYRROLE
  • 1-(TRIISOPROPYLSILYL)PYRROLE
  • N-TRIISOPROPYLSILYL PYRROLE
  • tri(propan-2-yl)-(1-pyrrolyl)silane
  • 1-[tris(propan-2-yl)silyl]-1H-pyrrole
  • 1-(Triisopropylsilyl)pyrrole 95%
  • 1H-Pyrrole, 1-[tris(1-Methylethyl)silyl]-
  • 1-(Triisopropylsilyl)-1H-pyrrole
CAS:
87630-35-1
MF:
C13H25NSi
MW:
223.43
Product Categories:
  • Pyrrole&Pyrrolidine&Pyrroline
  • Functional Materials
  • Pyrroles (for Conduting Polymer Research)
  • Reagents for Conducting Polymer Research
  • Si (Classes of Silicon Compounds)
  • Si-N Compounds
  • Trimethylsilylazide, etc.
  • Building Blocks
  • Heterocyclic Building Blocks
  • Pyrroles
Mol File:
87630-35-1.mol
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1-(TRIISOPROPYLSILYL)PYRROLE Chemical Properties

Boiling point:
78 °C0.4 mm Hg(lit.)
Density 
0.904 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.492(lit.)
Flash point:
224 °F
storage temp. 
Inert atmosphere,2-8°C
pka
-2.55±0.70(Predicted)
form 
clear liquid
color 
Colorless to Almost colorless
Specific Gravity
0.904
Water Solubility 
Not miscible in water.
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
BRN 
3540663
CAS DataBase Reference
87630-35-1(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20-22-36
Safety Statements 
24/25-26
WGK Germany 
3
HS Code 
2933998090

MSDS

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1-(TRIISOPROPYLSILYL)PYRROLE Usage And Synthesis

Uses

1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of:

  • ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate
  • heterocyclic base, 3-nitropyrrole
  • 3-nitropyrrole, required for the synthesis of 1 -(2′-deoxy-β-D-ribofuranosyl)-3-nitropyrrole

General Description

1-(Triisopropylsilyl)pyrrole (TISP), a heterocyclic building block, is a pyrrole derivative. TISP has been reported to generate pyrrolic cation radicals during cyclovoltammetric studies, via electroreduction. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).

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