N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos
N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Basic information
- Product Name:
- N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos
- Synonyms:
-
- N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos
- 98% Mor-DalPhos
- N-[2-(di-1-adaMantylphosphino)phenyl]Morpholine
- N-[2-(di-1-adaMantylphosphino)phenyl]Morpholine Mor-DalPhos
- Bis(adamant-1-yl)(2-morpholinophenyl)phosphine
- Di(1-adamantyl)-2-morpholinophenylphosphine
- 4-(2-(di(adamantan-1-yl)phosphanyl)phenyl)morpholine
- Bis(1-adamantyl)(2-morpholinophenyl)-phosphine (Mor-DalPhos)
- CAS:
- 1237588-12-3
- MF:
- C30H42NOP
- MW:
- 463.63
- Product Categories:
-
- Achiral Phosphine
- Aryl Phosphine
- organophosphine ligand
- Mol File:
- 1237588-12-3.mol
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N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Chemical Properties
- Melting point:
- 219-224°C
- storage temp.
- 2-8°C
- form
- crystal
- pka
- 4.75±0.40(Predicted)
- color
- white to yellow
- Sensitive
- air sensitive
- CAS DataBase Reference
- 1237588-12-3
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N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Usage And Synthesis
Reaction
- P-N-ligand for use in the Pd-catalyzed cross-coupling of ammonia and hydrazine. Ref. (2) with a diverse range of sterically hindered, unbiased aryl chlorides. Low catalyst loading and mild conditions. Ref (5) with diamines in a chemoselective arylation process. Ref (6) with solvent-free or aqueous conditions.
- P-N-ligand for the gold-catalyzed stereoselective hydroamination of internal alkynes with dialkylamines to afford E-amines.
- P-N-ligand for use in the Pd-catalyzed for mono-α-arylation of ketones employing aryl chlorides, bromides, iodides, mesylates (Ref. 7) and tosylates.
Uses
Mor-DalPhos is a versatile and efficient green catalytic system for Buchwald-Hartwig cross-coupling reaction of aryl bromides or chlorides with a large set amines, amides, ureas, and carbamates.
Uses
MorDalphos is an electronically rich, sterically hindered P,N-based ancillary ligand developed by the Stradiotto group that can be used in the Buchwald-Hartwig Amination reaction, alkyne hydroamination and monoarylation of compounds such as ammonia, hydrazine, and acetone.
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