BENZYLMAGNESIUM BROMIDE
BENZYLMAGNESIUM BROMIDE Basic information
- Product Name:
- BENZYLMAGNESIUM BROMIDE
- Synonyms:
-
- benzylbromomagnesium
- Benzylmagnesium Bromide (19% in Tetrahydrofuran, ca. 1mol/L)
- BENZYLMAGNESIUM BROMIDE
- Bromo(phenylmethyl)magnesium
- Bromobenzylmagnesium
- magnesium methanidylbenzene bromide
- Benzylmagnesium Bromide (ca. 12% in Tetrahydrofuran, ca. 0.6mol/L)
- BenzylMagnesiuM BroMide 1M in Tetrahydrofuran
- CAS:
- 1589-82-8
- MF:
- C7H7BrMg
- MW:
- 195.34
- EINECS:
- 216-459-7
- Product Categories:
-
- Grignard Reagent
- Classes of Metal Compounds
- Grignard Reagents
- Grignard Reagents & Alkyl Metals
- Mg (Magnesium) Compounds
- Synthetic Organic Chemistry
- Typical Metal Compounds
- Mol File:
- 1589-82-8.mol
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BENZYLMAGNESIUM BROMIDE Chemical Properties
- InChI
- InChI=1S/C7H7.BrH.Mg/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1
- InChIKey
- UHPSYHZSDNXIHK-UHFFFAOYSA-M
- SMILES
- C(C1C=CC=CC=1)[Mg]Br
- CAS DataBase Reference
- 1589-82-8
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BENZYLMAGNESIUM BROMIDE Usage And Synthesis
Uses
Benzylmagnesium Bromide is mainly used for the formation of diastereomeric o-toluylmethanol via a format reaction. Moreover, benzylmagnesium bromide only generates o-tolylmethanol when used in excess or at higher temperatures[1].
storage
Store under inert gas
References
[1] MARO\VS BELLA. Reaction of selected carbohydrate aldehydes with benzylmagnesium halides: benzyl versus o-tolyl rearrangement.[J]. Beilstein Journal of Organic Chemistry, 2014: 1942-1950. DOI:10.3762/bjoc.10.202.
BENZYLMAGNESIUM BROMIDESupplier
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- 010-88425576
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BENZYLMAGNESIUM BROMIDE(1589-82-8)Related Product Information
- Phenylmagnesium bromide
- 4-CHLOROPHENYLMAGNESIUM BROMIDE
- 4-FLUOROPHENYLMAGNESIUM BROMIDE
- 3,5-DICHLOROPHENYLMAGNESIUM BROMIDE
- 4-N-PROPYLPHENYLMAGNESIUM BROMIDE
- 4-BROMOBENZYLMAGNESIUM BROMIDE
- BENZYLMAGNESIUM BROMIDE
- 3,4-DIFLUOROBENZYLMAGNESIUM BROMIDE
- Benzylmagnesium Chloride,Benzylmagnesium Bromide
- 3,5-DIMETHYLBENZYLMAGNESIUM BROMIDE
- 2-BROMOBENZYLMAGNESIUM BROMIDE
- 2,5-DIFLUOROBENZYLMAGNESIUM BROMIDE
- A-STYRENYLMAGNESIUM BROMIDE
- 2,4-DIFLUOROBENZYLMAGNESIUM BROMIDE
- 4-TERT-BUTYLBENZYLMAGNESIUM BROMIDE
- 3-BROMOBENZYLMAGNESIUM BROMIDE
- (2-NAPHTHALENYLMETHYL)MAGNESIUM BROMIDE
- 4-(TRIFLUOROMETHOXY)BENZYLMAGNESIUM BROMIDE