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BENZYLMAGNESIUM BROMIDE

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BENZYLMAGNESIUM BROMIDE Basic information

Product Name:
BENZYLMAGNESIUM BROMIDE
Synonyms:
  • benzylbromomagnesium
  • Benzylmagnesium Bromide (19% in Tetrahydrofuran, ca. 1mol/L)
  • BENZYLMAGNESIUM BROMIDE
  • Bromo(phenylmethyl)magnesium
  • Bromobenzylmagnesium
  • magnesium methanidylbenzene bromide
  • Benzylmagnesium Bromide (ca. 12% in Tetrahydrofuran, ca. 0.6mol/L)
  • BenzylMagnesiuM BroMide 1M in Tetrahydrofuran
CAS:
1589-82-8
MF:
C7H7BrMg
MW:
195.34
EINECS:
216-459-7
Product Categories:
  • Grignard Reagent
  • Classes of Metal Compounds
  • Grignard Reagents
  • Grignard Reagents & Alkyl Metals
  • Mg (Magnesium) Compounds
  • Synthetic Organic Chemistry
  • Typical Metal Compounds
Mol File:
1589-82-8.mol
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BENZYLMAGNESIUM BROMIDE Chemical Properties

InChIKey
UHPSYHZSDNXIHK-UHFFFAOYSA-M
CAS DataBase Reference
1589-82-8
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Safety Information

RIDADR 
2924
HazardClass 
3/8
PackingGroup 
II
HS Code 
29319090
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BENZYLMAGNESIUM BROMIDE Usage And Synthesis

Uses

Benzylmagnesium Bromide is mainly used for the formation of diastereomeric o-toluylmethanol via a format reaction. Moreover, benzylmagnesium bromide only generates o-tolylmethanol when used in excess or at higher temperatures[1].

storage

Store under inert gas

References

[1] MARO\VS BELLA. Reaction of selected carbohydrate aldehydes with benzylmagnesium halides: benzyl versus o-tolyl rearrangement.[J]. Beilstein Journal of Organic Chemistry, 2014: 1942-1950. DOI:10.3762/bjoc.10.202.

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