ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organic rhodium > (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Basic information
- Product Name:
- (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
- Synonyms:
-
- ：(R,R)-(-)-1,2-Bis[(
- (R,R)-(-)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane(1,5-cyclooctadiene)rhodium(I) terafluoroborate
- (r,r)-(-)-1,2-bis((2-Methoxyphenyl)phenylphosphino)ethane(1,5-cy
- (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)
rhodium (I)tetrafluoroborate, min. 95% - (R,R)-(-)-1,2-Bis[(o-Methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,95%
- Chiralyst Rh756
- (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)
- (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)phenylphosphino]ethane(1,5-cyclooctadiene)rho
- CAS:
- 56977-92-5
- MF:
- C36H38BF4O2P2Rh
- MW:
- 754.35
- Product Categories:
-
- metal-phosphine complexes
- Rh
- Mol File:
- 56977-92-5.mol
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(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Chemical Properties
- form
- Powder
- color
- orange
- Sensitive
- air sensitive
- CAS DataBase Reference
- 56977-92-5
MSDS
- Language:English Provider:ACROS
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(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Usage And Synthesis
Reaction
- Highly reactive enantioselective catalyst for the asymmetric hydrogenation of various substituted dehydroalanines to Nprotected aminoacids. Also, catalyst is very effective in the asymmetric reduction of pentapetides that contain unsaturated Phe or Tyr linkages to enkephalin, a brain peptide hormone.
- Efficient catalyst for the asymmetric reduction of enol acetates to esters.
- Catalyst used to prepare chiral 2-substituted succinic acid derivatives.
Chemical Properties
Orange crystalline powder
Uses
(R,R)-(-)-1,2-Ethanediylbis[(2-methoxyphenyl)phenylphosphine]rhodium(I) Tetrafluoroborate is used as a catalyst in the synthesis of Sinefungin (S487100); a natural nucleoside analog of S-adenosylmethionine that inhibits Streptococcus pneumoniae biofilm growth. Its derivatives can be used as inhibitors and structure probes for human protein lysine methyltransferase SETD2.
(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATESupplier
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(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE(56977-92-5)Related Product Information
- (S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE
- Fluoroboric acid
- (R,R)-DIPAMP
- Rhodium
- (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
- 1,5-Cyclooctadiene
- 1,2-Bis(diphenylphosphino)ethane
- 1,2-BIS(PHENYLPHOSPHINO)ETHANE
- 1,2-BIS[(2-METHOXYPHENYL)PHENYLPHOSPHINO]ETHANE
- METHYLPHOSPHINE BORANE COMPLEX
- BORANE-DIPHENYLPHOSPHINE COMPLEX
- BIS(2-METHOXYPHENYL)PHENYLPHOSPHINE
- (S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 95%
- (S,S)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
- 2-METHOXYPHENYLPHOSPHINE