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ChemicalBook >  Product Catalog >  Organic Chemistry >  Organometallic compounds >  Organic rhodium >  (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

Basic information Reaction Safety Supplier Related

(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Basic information

Product Name:
(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
Synonyms:
  • :(R,R)-(-)-1,2-Bis[(
  • (R,R)-(-)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane(1,5-cyclooctadiene)rhodium(I) terafluoroborate
  • (r,r)-(-)-1,2-bis((2-Methoxyphenyl)phenylphosphino)ethane(1,5-cy
  • (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)
    rhodium (I)tetrafluoroborate, min. 95%
  • (R,R)-(-)-1,2-Bis[(o-Methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,95%
  • Chiralyst Rh756
  • (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)
  • (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)phenylphosphino]ethane(1,5-cyclooctadiene)rho
CAS:
56977-92-5
MF:
C36H38BF4O2P2Rh
MW:
754.35
Product Categories:
  • metal-phosphine complexes
  • Rh
Mol File:
56977-92-5.mol
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(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Chemical Properties

form 
Powder
color 
orange
Sensitive 
air sensitive
CAS DataBase Reference
56977-92-5
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Safety Information

Risk Statements 
36/37/38
Safety Statements 
24/25-22
HS Code 
29319019

MSDS

  • Language:English Provider:ACROS
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(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Usage And Synthesis

Reaction

  1. Highly reactive enantioselective catalyst for the asymmetric hydrogenation of various substituted dehydroalanines to Nprotected aminoacids. Also, catalyst is very effective in the asymmetric reduction of pentapetides that contain unsaturated Phe or Tyr linkages to enkephalin, a brain peptide hormone.
  2. Efficient catalyst for the asymmetric reduction of enol acetates to esters.
  3. Catalyst used to prepare chiral 2-substituted succinic acid derivatives.

Chemical Properties

Orange crystalline powder

Uses

(R,R)-(-)-1,2-Ethanediylbis[(2-methoxyphenyl)phenylphosphine]rhodium(I) Tetrafluoroborate is used as a catalyst in the synthesis of Sinefungin (S487100); a natural nucleoside analog of S-adenosylmethionine that inhibits Streptococcus pneumoniae biofilm growth. Its derivatives can be used as inhibitors and structure probes for human protein lysine methyltransferase SETD2.

(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATESupplier

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