Methyl 2-((2R,4aS,6S,7R,8S,8aS)-7,8-bis((tert-butyldimethylsilyl)oxy)-6-((S,E)-1-((tert-butyldimethylsilyl)oxy)-3-iodoallyl)octahydropyrano[3,2-b]pyran-2-yl)acetate
Methyl 2-((2R,4aS,6S,7R,8S,8aS)-7,8-bis((tert-butyldimethylsilyl)oxy)-6-((S,E)-1-((tert-butyldimethylsilyl)oxy)-3-iodoallyl)octahydropyrano[3,2-b]pyran-2-yl)acetate Basic information
- Product Name:
- Methyl 2-((2R,4aS,6S,7R,8S,8aS)-7,8-bis((tert-butyldimethylsilyl)oxy)-6-((S,E)-1-((tert-butyldimethylsilyl)oxy)-3-iodoallyl)octahydropyrano[3,2-b]pyran-2-yl)acetate
- Synonyms:
-
- Eribulin mesylate intermediate
- Eribulin mesylate intermediate1
- Eribulin intermediate ERA
- L-arabino-D-allo-Tridec-12-enonic acid, 3,7:6,10-dianhydro-2,4,5,12,13-pentadeoxy-8,9,11-tris-O-[(1,1-dimethylethyl)dimethylsilyl]-13-iodo-, methyl ester, (12E)-
- Eribulin intermediate A
- methyl 2-((2R,4aS,6S,7R,8S,8aS)-7,8-bis(tert-butyldimethylsilyloxy)-6-((S,E)-1-(tert-butyldimethylsilyloxy)-3-iodoallyl)octahydropyrano[3,2-b]pyran-2-yl)acetate
- ((2R,4aS,6S,7R,8S,8aS)-7,8-bis((tert-butyldimethylsilyl)oxy)-6-((S,E)-1-((tert-butyldimethylsilyl)oxy)-3-iodoallyl)octahydropyrano[3,2-b]pyran-2-yl)acetate
- (12E)-3,7:6,10-Dianhydro-2,4,5,12,13-pentadeoxy-8,9,11-tris-O-[(1,1-dimethylethyl)dimethylsilyl]-13-iodo-L-arabino-D-allo-tridec-12-enonic acid methyl ester
- CAS:
- 157322-83-3
- MF:
- C32H63IO7Si3
- MW:
- 771.01
- Product Categories:
-
- Intermediates
- 157322-83-3
- Mol File:
- 157322-83-3.mol
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Methyl 2-((2R,4aS,6S,7R,8S,8aS)-7,8-bis((tert-butyldimethylsilyl)oxy)-6-((S,E)-1-((tert-butyldimethylsilyl)oxy)-3-iodoallyl)octahydropyrano[3,2-b]pyran-2-yl)acetate Chemical Properties
- Boiling point:
- 608.3±55.0 °C(Predicted)
- Density
- 1.14±0.1 g/cm3(Predicted)
- CAS DataBase Reference
- 157322-83-3
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Methyl 2-((2R,4aS,6S,7R,8S,8aS)-7,8-bis((tert-butyldimethylsilyl)oxy)-6-((S,E)-1-((tert-butyldimethylsilyl)oxy)-3-iodoallyl)octahydropyrano[3,2-b]pyran-2-yl)acetate Usage And Synthesis
Uses
Methyl 2-((2R,4aS,6S,7R,8S,8aS)-7,8-bis((tert-butyldimethylsilyl)oxy)-6-((S,E)-1-((tert-butyldimethylsilyl)oxy)-3-iodoallyl)octahydropyrano[3,2-b]pyran-2-yl)acetate, is an intermediate in the synthesis of Eribulin mesylate (E615203), a synthetic analog of the marine natural product halichondrin B.
Methyl 2-((2R,4aS,6S,7R,8S,8aS)-7,8-bis((tert-butyldimethylsilyl)oxy)-6-((S,E)-1-((tert-butyldimethylsilyl)oxy)-3-iodoallyl)octahydropyrano[3,2-b]pyran-2-yl)acetateSupplier
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Methyl 2-((2R,4aS,6S,7R,8S,8aS)-7,8-bis((tert-butyldimethylsilyl)oxy)-6-((S,E)-1-((tert-butyldimethylsilyl)oxy)-3-iodoallyl)octahydropyrano[3,2-b]pyran-2-yl)acetate(157322-83-3)Related Product Information
- Methanesulfonic acid, trifluoro-, (2R,4R)-4-hydroxy-2-methyl-1-methylene-6-[(2S,5S)-tetrahydro-5-(3-hydroxypropyl)-3-methylene-2-furanyl]hexyl ester (9CI)
- a-D-xylo-Hept-6-enofuranose, 5,6,7-trideoxy-1,2-O-(1-Methylethylidene)-
- (3aR,5R,6S,6aR)-5-allyl-6-methoxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxole
- D-glycero-D-gulo-Dec-1-enitol, 4,7-anhydro-1,2,3,8-tetradeoxy-6-O-(phenylmethyl)-, 9,10-dibenzoate
- (3aR,5R,6S,6aR)-5-(2-hydroxy-3-(trimethylsilyl)propyl)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-6-ol
- (5R)-5-hydroxy-7-((5S)-5-(3-hydroxypropyl)-3-methylenetetrahydrofuran-2-yl)-3-methylhept-1-en-2-yl trifluoromethanesulfonate
- (S)-3-((2R,3R,4R,5S)-5-allyl-3-hydroxy-4-((phenylsulfonyl)methyl)tetrahydrofuran-2-yl)propane-1,2-diol
- methyl 2-((2R,4aS,6S,7R,8S,8aS)-7,8- bis((tert-butyldimethylsilyl)oxy)-6-((S,E)-1- ((tert-butyldimethylsilyl)oxy)-3- (trimethylsilyl)allyl)octahydropyrano [3,2- b]pyran-2-yl)acetate
- (S)-3-((2R,3R,4S,5S)-5-allyl-4-hydroxy-3-methoxytetrahydrofuran-2-yl)propane-1,2-diyl dibenzoate
- (R)-2-iodo-3-(iodomethyl)but-1-ene
- Eribulin Mesylate
- Eribulin
- 3,6-Anhydro-2,4,7-trideoxy-8,9-bis-O-[(1,1-dimethylethyl)dimethylsilyl]-5-O-methyl-4-[(phenylsulfonyl)methyl]-D-glycero-D-gulo-nonose
- (2-Furanpropanol, 5-[2-[(2S,4R,6R)-6-[[(2S,3S,4R,5R)-5-[(2S)-2,3-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]propyl]tetrahydro-4-methoxy-3-[(phenylsulfonyl) methyl]-2-furanyl]methyl]tetrahydro-4-methyl-5-methylene-2H-pyran-2-yl]ethyl]
- CAL-101
- Eribulin intermediate
- Propanoic acid, 2,2-dimethyl-, 3-[(2S,5S)-tetrahydro-4-methylene-5-[(3R,5R)-5-methyl-3-[(methylsulfonyl)oxy]-6-[[(trifluoromethyl)sulfonyl]oxy]-6-hepten-1-yl]-2-furanyl]propyl ester