Tris(dibenzylideneacetone)dipalladium Chemical Properties

Melting point:

152-155 °C(lit.)

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

solubility 

Chloroform (Sparingly, Sonicated), DMSO (Slightly, Sonicated), Methanol (Slightly, Sonicated)

form 

Solid

color 

Dark Red to Black

InChI

InChI=1S/3C17H14O.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;;/h3*1-14H;;/b3*13-11+,14-12+;;

InChIKey

CYPYTURSJDMMMP-WVCUSYJESA-N

SMILES

C1(=CC=CC=C1)/C=C/C(/C=C/C1=CC=CC=C1)=O.C1(=CC=CC=C1)/C=C/C(=O)/C=C/C1=CC=CC=C1.C1(=CC=CC=C1)/C=C/C(=O)/C=C/C1=CC=CC=C1.[Pd].[Pd]

Safety Information

Safety Statements 

24/25

WGK Germany 

3

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

Tris(dibenzylideneacetone)dipalladium Usage And Synthesis

Uses

Tris(dibenzylideneacetone)dipalladium is used in the preparation of semiconducting polymers processed from nonchlorinated solvents into high performance thin film transistors. Also used in the synthesis of polymer bulk-heterojunction solar sells as a semiconductor.

Synthesis

Palladium acetate was dissolved in dichloromethane; dibenzylidene acetone was dissolved in anhydrous ethanol and toluene (1:1); a homemade redox resin was used to fill a two-stage 5L reactor; the palladium solution and the dibenzylidene acetone solution were added proportionally at 100??C to pass through the two-stage reactor at 5 ml/min; the product was condensed and crystallized using condensate, and the liquid was transferred to the previous step for the next reaction. The elemental analysis of the obtained product was C:66.72%, H:4.71%; Pd,content was 23.36%, the purity of the product was more than 99%, and the primary yield was 89%.

Tris(dibenzylideneacetone)dipalladium(60748-47-2)Related Product Information

• Tris(triphenylphosphine)chlororhodium
• Phosphorus oxitrichloride
• Carbonylchlorohydrotris(triphenylphosphine)ruthenium
• Cuprous iodide
• Tris(dibenzylideneacetone)dipalladium
• Bis(triphenylphosphinepalladium) acetate
• BIS(3 5 3' 5'-DIMETHOXYDIBENZYLIDENEACE&
• TRANS-DICHLOROBIS(TRIETHYLPHOSPHINE)PALLADIUM(II)
• Bis(tricyclohexylphosphine)palladium(II) Dichloride
• Tris(dibenzylideneacetone)dipalladium-chloroform adduct
• dichlorobis(di-tert-butylphenylphosphine)palladium(II)
• Selenium dioxide
• 3-Phenylpropionic acid
• Bis(dibenzylideneacetone)palladium
• Tris(dibenzylideneacetone)dipalladium
• Dibenzylideneacetone
• trans,trans-Dibenzylideneacetone