Basic information Description Reference Safety Supplier Related
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4-Carboxyphenylboronic acid

Basic information Description Reference Safety Supplier Related

4-Carboxyphenylboronic acid Basic information

Product Name:
4-Carboxyphenylboronic acid
Synonyms:
  • 4-borono-benzoicaci
  • AKOS BRN-0008
  • RARECHEM AH PB 0147
  • TIMTEC-BB SBB003899
  • OTAVA-BB BB7110951390
  • P-CARBOXYPHENYLBORONIC ACID
  • ZERENEX ZX001647
  • 4-(Dihydroxyboronyl)benzoic acid, 4-Boronobenzoic acid
CAS:
14047-29-1
MF:
C7H7BO4
MW:
165.94
EINECS:
604-189-6
Product Categories:
  • Boric Acid| Boric Acid Ester| Potassium Trifluoroborate| carboxylic acid
  • Boronate Ester
  • B (Classes of Boron Compounds)
  • organic or inorganic borate
  • Plant extract
  • Potassium Trifluoroborate
  • Substituted Boronic Acids
  • Heterocyclic Compounds
  • Boronic Acid
  • Aryl
  • Organoborons
  • CHIRAL CHEMICALS
  • Boronic Acids & Esters
  • Phenyls & Phenyl-Het
  • blocks
  • BoronicAcids
  • Carboxes
  • Boronic Acid series
  • Boronic Acids & Esters
  • Phenyls & Phenyl-Het
  • Boronic acids
Mol File:
14047-29-1.mol
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4-Carboxyphenylboronic acid Chemical Properties

Melting point:
220 °C (dec.) (lit.)
Boiling point:
406.4±47.0 °C(Predicted)
Density 
1.40±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly), Water (Slightly)
pka
4.08±0.10(Predicted)
form 
Powder
color 
Off-white to light beige
BRN 
3031088
InChI
InChI=1S/C7H7BO4/c9-7(10)5-1-3-6(4-2-5)8(11)12/h1-4,11-12H,(H,9,10)
InChIKey
SIAVMDKGVRXFAX-UHFFFAOYSA-N
SMILES
C(O)(=O)C1=CC=C(B(O)O)C=C1
CAS DataBase Reference
14047-29-1(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
37/39-26-36
WGK Germany 
2
RTECS 
CY8925000
TSCA 
No
HazardClass 
IRRITANT
HS Code 
29319090

MSDS

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4-Carboxyphenylboronic acid Usage And Synthesis

Description

4-Carboxyphenylboronic acid is a highly versatile reagent. It is a reagent used in various reactions including condensation reactions with stabilizer chains at the surface of polystyrene latex, Suzuki coupling reactions, esterification, derivatization of polyvinylamine, synthesis of isotopically labeled mercury and functionalization of poly-SiNW for detection of dopamine. It is reagents used for Suzuki-Miyaura cross-coupling, induction of pH sensitivity on fluorescence lifetime of quantum dots by NIR fluorescent dyes, bio-supported palladium nanoparticles as phosphine-free catalyst for Suzuki reaction in water and Chan-Lam-type Copper (Cu)-catalyzed S-arylation with aryl boronic acids at room temperature. It is reagents used for the preparation of isoquinolones via regioselective Suzuki-Miyaura cross-coupling and tandem palladium-catalyzed intramolecular aminocarbonylation and annulation, amprenavir-based P1-substituted bi-aryl derivatives as ultra-potent HIV-1 protease inhibitors, phenols via visible-light initiated aerobic oxidative hydroxylation of arylboronic acids using air as oxidant catalyzed by Ruthenium (Ru)-complex, glucose sensitive boronic acid-bearing block copolymers, trisulfonated calixarene upper-rim sulfonamido derivatives and their complexation with the trimethyllysine epigenetic mark. It can also be used as a corrosion inhibitor for steel.

Reference

  1. Nam, N. D., et al. "A study of 4-carboxyphenylboronic acid as a corrosion inhibitor for steel in carbon dioxide containing environments." Corrosion Science 76.10(2013):257-266.
  2. Vollmueller, Frank, et al. "Cyclization of 4-carboxyphenylboronic acid with hydrazide derivative; hydrolysis; catalytic esterification." US, US 6197967 B1. 2001.

Chemical Properties

Off-white to light beige powder

Uses

suzuki reaction

Uses

4-Carboxyphenylboronic acid is a reagent used in suzuki coupling reactions.

Uses

Intermediates of Liquid Crystals

4-Carboxyphenylboronic acid Preparation Products And Raw materials

Preparation Products

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