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(R)-SpiroPAP-Me-Ir

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(R)-SpiroPAP-Me-Ir Basic information

Product Name:
(R)-SpiroPAP-Me-Ir
Synonyms:
  • (R)-SpiroPAP-Me-Ir
  • [N-[(1R)-7'-[BIS[3,5-BIS(TERT-BUTYL)PHENYL]PHOSPHINO-ΚP]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDEN]-7-YL]-3-METHYL-2-PYRIDINEMETHANAMINE-ΚN1,ΚN2]CHLORODIHYDRO-IRIDIUM
  • Ir-(R)-DTB-SpiroPAP-3-Me
  • CHLORODIHYDRIDO{(R)-(+)-7-BIS(3,5-DI-T-BUTYLPHENYL)PHOSPHINO-7'-[(3-METHYLPYRIDINE-2-YLMETHYL)AMINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE}IRIDIUM(III),>97%(>99%EE)IR-(R)-DTB-SPIROPAP-3-ME
  • 99% ee) Ir-(R)-DTB-SpiroPAP-3-Me
  • Chlorodihydrido{(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(3-methylpyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane}iridium(III), >
  • 97% (>
  • Ir-(R)-DTB-SpiroPAP-3-Me,[N-[(1R)-7'-[BIS[3,5-BIS(TERT-BUTYL)PHENYL]PHOSPHINO-ΚP]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDEN]-7-YL]-3-METHYL-2-PYRIDINEMETHANAMINE-ΚN1,ΚN2]CHLORODIHYDRO-IRIDIUM
CAS:
1396201-63-0
MF:
C52H67ClIrN2P
MW:
978.76
Product Categories:
  • Chiral Phosphine
  • Chiral Spiro Ligand
  • Ir
Mol File:
1396201-63-0.mol
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(R)-SpiroPAP-Me-Ir Chemical Properties

form 
solid
color 
yellow-green
CAS DataBase Reference
1396201-63-0
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(R)-SpiroPAP-Me-Ir Usage And Synthesis

Reaction

  1. Catalyst for the enantioselective synthesis of chiral disubstituted oxa-cyclic ethers
  2. Catalyst for the enantioselective hydrogenation for the asymmetric synthesis of Rivastigmine
  3. Catalyst for the asymmetric hydrogenation for the synthesis of Crizotinib
  4. Catalyst for the asymmetric hydrogenation of α-keto acids
  5. Catalyst for the kinetic resolution of racemic aliphatic alcohols via selective asymmetric hydrogenation

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