LINALYL BENZOATE
LINALYL BENZOATE Basic information
- Product Name:
- LINALYL BENZOATE
- Synonyms:
-
- 1,5-dimethyl-1-vinyl-4-hexen-1-obenzoate
- 1,5-dimethyl-1-vinyl-4-hexen-1-ylbenzoate
- 1,6-Octadien-3-ol,3,7-dimethyl-,benzoate
- 3,7-dimethyl-1,6-octadien-3-ylbenzoate
- 6-octadien-3-ol,3,7-dimethyl-benzoate
- benzoicacid,linalylester
- Linalylbenzoat
- 1,6-OCTADIEN-3-OL, 3,7-DIMETHYL-, BENZOATE,94%, GLC
- CAS:
- 126-64-7
- MF:
- C17H22O2
- MW:
- 258.36
- EINECS:
- 204-796-2
- Product Categories:
-
- Alphabetical Listings
- Flavors and Fragrances
- I-L
- Mol File:
- 126-64-7.mol
LINALYL BENZOATE Chemical Properties
- Boiling point:
- 213 °C(lit.)
- Density
- 0.98 g/mL at 25 °C(lit.)
- FEMA
- 2638 | LINALYL BENZOATE
- refractive index
- n20/D 1.508(lit.)
- Flash point:
- >230 °F
- Odor
- at 100.00 %. floral bergamot genet herbal tuberose tropical lily plum ylang grape
- Odor Type
- floral
- JECFA Number
- 859
- LogP
- 6.14
- CAS DataBase Reference
- 126-64-7
- EPA Substance Registry System
- 1,6-Octadien-3-ol, 3,7-dimethyl-, benzoate (126-64-7)
MSDS
- Language:English Provider:SigmaAldrich
LINALYL BENZOATE Usage And Synthesis
Aroma
Balsamic-floral, Bergamot-fruity odor of good tenacity. The odor varies considerably according to the method of production of this ester. Above description is based upon the "Roche"-processed material, while older methods yield esters of far greater sweetness, less tenacity and more similarity to Linalyl acetate, often with side-notes of Methylbenzoate. Peculiar, deep-sweet, fruity or fruit-preservelike odor, mainly of Plum-type.
Description
Linalyl benzoate has a heavy odor reminiscent of genet, bergamc and lily. It may be prepared from linalool and benzoyl chloride the presence of pyridine.
Chemical Properties
Linalyl benzoate has a heavy odor reminiscent of floral, balsamic and fruity.
Occurrence
Reported found in the essential oils of ylang-ylang and tuberose; also in mushrooms.
Definition
ChEBI: Linalyl benzoate is a monoterpenoid.
Production Methods
Linalyl benzoate can be produced: 1) from Linalyl formate plus Methylanthranilate with Sodium Linalool. 2) by esterification of Dehydrolinalool with Benzoic acid e.g. under azeotropic conditions, followed by hydrogenation of the Dehydro-ester. 3) from Linalool sodium with Trichloro acetophenone.
Preparation
From linalool and benzoyl chloride in the presence of tuberose.
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