XantPhos Pd G4 Chemical Properties

form 

solid

color 

yellow

InChI

InChI=1S/2C39H32O4P2S.C13H12N.CH4.Pd/c2*1-39(2)32-24-15-25-33(44(28-16-7-3-8-17-28)29-18-9-4-10-19-29)37(32)43-38-34(26-27-35(36(38)39)46(40,41)42)45(30-20-11-5-12-21-30)31-22-13-6-14-23-31;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;;/h2*3-27H,1-2H3,(H,40,41,42);2-7,9-10,14H,1H3;1H4;/q;;;;+1/p-2

InChIKey

YEBRPYRJQFPKNJ-UHFFFAOYSA-L

SMILES

C1(C)(C)C2=C(C(P(C3=CC=CC=C3)C3=CC=CC=C3)=CC=C2)OC2=C1C(S([O-])(=O)=O)=CC=C2P(C1=CC=CC=C1)C1=CC=CC=C1.C1(C)(C)C2=C(C(P(C3=CC=CC=C3)C3=CC=CC=C3)=CC=C2)OC2=C1C(S([O-])(=O)=O)=CC=C2P(C1=CC=CC=C1)C1=CC=CC=C1.[Pd+]C1=CC=CC=C1C1=CC=CC=C1NC.C

CAS DataBase Reference

1621274-19-8

XantPhos Pd G4 Usage And Synthesis

Uses

A powerful ligand for classic cross-coupling reactions combined with the Buchwald Fourth Generation Palladacycle. Bench stable, soluble in most organic solvents.

Reactions

1. Catalyst used in the aminocarbonylation of (hetero)aryl bromides.
2. Catalyst used in the aminocarbonylation of bromopyridine and alkyl-substituted bromobenzene.

XantPhos Pd G4(1621274-19-8)Related Product Information

• VPhos Pd G4
• RockPhos Pd G3
• t-BuBrettPhos Palladacycle Gen. 3
• cataCXium A Pd G3
• EPhos Pd G4
• Methanesulfonato(triphenylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) (PPH3 PD G3)
• RuPhos Pd G3
• tBuXPhos-Pd-G3
• Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
• XPhos Pd G3
• SPhos Pd G3
• Xantphos Pd G3
• BrettPhos Pd G3
• BrettPhos Pd G4
• Methanesulfonato(Di-tert-butyl(2',4',6'-triispropyl-3,6-dimethoxybiphenyl-2-yl)phosphine)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
• SPhos Palladacycle Gen. 4
• XPhos Pd G4
• t-BuXphos Palladacycle Gen. 4