Basic information Reaction Safety Supplier Related

hexafluorophosphate

Basic information Reaction Safety Supplier Related

hexafluorophosphate Basic information

Product Name:
hexafluorophosphate
Synonyms:
  • bis[3,5-Difluoro-2-[5-(trifluoromethyl)-2-pyridyl]phenyl]ruthenium(1+)
  • (4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate
  • 4-tert-butyl-2-(4-tert-butyl-2-pyridyl)pyridine
  • Ir[dF(CF3)ppy]2(dtbbpy)PF6
  • (4,4'-DI-T-BUTYL-2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-TRIFLUOROMETHYL-2-PYRIDINYL-KN)PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE,99%
  • [Ir(dtbbpy)[dF(CF3)ppy]2]PF6
  • 4,4-Bis(tert-butyl)-2,2-bipyridine]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]Iridium(III)hexafluorophosphate
  • (4,4'-Di-t-butyL
CAS:
870987-63-6
MF:
C42H34F10IrN4.PF6
MW:
1121.91
Mol File:
870987-63-6.mol
More
Less

hexafluorophosphate Chemical Properties

Melting point:
>300 °C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Chloroform (Slightly)
form 
crystal
color 
yellow
CAS DataBase Reference
870987-63-6
More
Less

Safety Information

Risk Statements 
36/37/38
Safety Statements 
26
TSCA 
No
HS Code 
2843909000
More
Less

hexafluorophosphate Usage And Synthesis

Reaction

  1. Visible light photoredox-catalyzed cascade cyclizations of α-bromochalcones or α-bromocinnamates with heteroarenes.
  2. Enantioselective α-benzylation of aldehydes via photoredox organocatalysis.

Uses

(Ir[dF(CF3)ppy]2(dtbpy))PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.It has been used to achieve late-stage incorporation of alkyl groups to a variety of biologically active heterocycles.

Uses

[4,?4''-?Bis(tert-butyl)?-?2,?2''-?bipyridine]?bis[3,?5-?difluoro-?2-?[5-?(trifluoromethyl)?-?2-?pyridinyl]?phenyl]?iridium(III) hexafluorophosphate is commonly used as a catalyst in the synthesis of various compounds such as saturated N-?heterocycles from aldehydes, fosmidomycin analogue, and many more.

hexafluorophosphateSupplier

Energy Chemical Gold
Tel
021-021-58432009 400-005-6266
Email
sales8178@energy-chemical.com
Panjin Infinity Scientific CO. LTD Gold
Tel
400-1062016 18612996721
Email
hao@infsci.com
Changzhou Carman Chemical Co., ltd Gold
Tel
0519-0519-83534936 18151214939
Email
1521178147@qq.com
Jiangsu aikang biomedical research and development co., LTD Gold
Tel
025-66110311 13155353615
Email
qzhang@aikonchem.com
Tianjin Kailiqi Biotechnology Co., Ltd. Gold
Tel
15076683720
Email
klq@cw-bio.com