Ir[dFppy]2(dtbbpy)PF6 Chemical Properties

Melting point:

>300°C

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

form 

powder or crystals

Appearance

Light yellow to yellow Solid

InChIKey

YTFMVASKFDAIDY-UHFFFAOYSA-N

SMILES

[P+5]([F-])([F-])([F-])([F-])([F-])[F-].FC1C=C(F)C=[C-]2[Ir+3]34(N5=CC=CC=C5C5=C(C=C(F)C=[C-]35)F)(N3=CC=C(C(C)(C)C)C=C3C3=CC(C(C)(C)C)=CC=N43)N3=CC=CC=C3C=12

Ir[dFppy]2(dtbbpy)PF6 Usage And Synthesis

Uses

This photocatalyst readily facilitates alkynylation of carboxylic acids as well as the decarboxylative cross-coupling of oxalates via metallaphotoredox catalysis.

reaction suitability

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

Ir[dFppy]2(dtbbpy)PF6(1072067-44-7)Related Product Information

• Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium(III)
• Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III)
• Ir[dF(t-Bu)-ppy]3
• (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate
• Iridium
• [2,2'-bis (4-tert-butylpyridine)] bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate
• (2,2'-bipyridyl) bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate
• Tris (2- (4-tert-butylphenyl) pyridine) iridium
• Ir[dF(Me)ppy]2(dtbbpy)PF6
• Ir(dFppy)3
• (2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) Hexafluorophosphate
• Ir[p-F(t-Bu)-ppy]3
• [Ir{dFCF3ppy}2(bpy)]PF6
• [Ir(dtbbpy)(ppy)2][PF6]
• Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [1,10-phenanthroline] iridium hexafluorophosphate
• hexafluorophosphate
• Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-)
• Ir[p-F(Me)ppy]2(dtbbpy)PF6