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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Basic information

Product Name:
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
Synonyms:
  • DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]-PALLADIUM DICHLOROMETHANE ADDUCT
  • DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHANE ADDUCT
  • DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHANE COMPLEX
  • 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE, DICHLOROMETHANE
  • 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE-PALLADIUM(II)DICHLORIDE DICHLOROMETHANE COMPLEX
  • [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II), COMPLEX WITH DICHLOROMETHANE (1:1)
  • 1'1-Bis(diphenylphosphino)fewocene Palladium(Ⅱ)chloride dichloromethane chloride
  • 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichlorome
CAS:
95464-05-4
MF:
C34H28Cl2FeP2Pd.CH2Cl2
MW:
816.63
EINECS:
619-128-9
Product Categories:
  • Pd
  • Catalysis and Inorganic Chemistry
  • Homogeneous Pd Catalysts
  • Palladium
Mol File:
95464-05-4.mol
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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Chemical Properties

Melting point:
275-280 °C(lit.)
Density 
1 g/cm3
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Powder
color 
orange-red
Water Solubility 
Insoluble in water.
Stability:
Light Sensitive
CAS DataBase Reference
95464-05-4(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38-40-67-48/20/22
Safety Statements 
23-24/25-26-36/37
WGK Germany 
3
TSCA 
No
HS Code 
28439000

MSDS

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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Usage And Synthesis

Reaction

  1. Catalyst for the borylation of aryl halides.
  2. β-Alkyl Suzuki-Miyaura cross-coupling reactions with potassium alkyltrifluoroborates.
  3. Catalyst for modified Negishi coupling.
  4. Synthesis of polyheterocycles by a Pd-catalyzed intramolecular N-arylation/C-H bond activation/aryl-aryl bond-forming domino process.
  5. Catalyst for Stille allylation.
  6. Catalyst for the amination of aryl bromides.

Chemical Properties

orange/red solid

Uses

suzuki reaction

Uses

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is used in the preparation of imidazoles, benzimidazoles, and tetrahydropyrimidines,it is also used as a catalyst for Suzuki and Stile couplings.

Application

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is an organometallic compound that can be used as a noble metal catalyst for carbonylation reactions, cross-coupling reactions, Suzuki reaction.

Synthesis

1. Dissolve 2.00 grams of sodium palladium chloride in 30mL of anhydrous ethanol to obtain the ethanol solution of sodium palladium chloride;
2. Dissolve 4.15 grams of 1,1 '-bis (diphenylphosphine) ferrocene in 41mL dichloromethane to obtain 1,1' -bis (diphenylphosphine) ferrocene dichloromethane solution;
3. Under stirring conditions, add the ethanol solution of sodium palladite chloride in step 1 to dichloromethane solution of 1, 1 '-bis (diphenylphosphine) ferrocene in step 2. Stir and react for 1h at 25℃. 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex crystal, yield 90.46%.
In this method, the target product 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex was synthesized directly with dichloromethane as the solvent in one step, eliminating the synthesis process of precursor PDCl2 (DPPF). The reaction process is simple, the synthesis cycle is short, easy to operate, and the purity of the synthesized product is 99.4%.

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Preparation Products And Raw materials

Raw materials

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complexSupplier

Shaanxi Rock New Materials Co., Ltd. Gold
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917-917-8888777 18691746767
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zhaoting@bjrock.com
WuHan Taiyukaishang Chemical Co., Ltd. Gold
Tel
027-87680032 18963957250
Email
355723431@qq.com
Wu Han Lbpchem Chemical Co., Ltd. Gold
Tel
02763499399 13797220777
Email
lpbchem@163.com
Beijing Guofang Dingsheng Technology Co., Ltd. Gold
Tel
0316-6175846 18610472091
Email
gfdschem@126.com
Beijing Bainiannuan Sci.&Tec. Co., Ltd Gold
Tel
10-51765162 13240490036
Email
marymeng@bdnchem.com