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Picramic acid

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Picramic acid Basic information

Product Name:
Picramic acid
Synonyms:
  • fourrine93
  • Furro 4R
  • furro4r
  • Oxidation Base 21
  • Phenol, 2-amino-4,6-dinitro-
  • picramic
  • Zoba 4R
  • zoba4r
CAS:
96-91-3
MF:
C6H5N3O5
MW:
199.12
EINECS:
202-544-6
Product Categories:
  • Intermediates of Dyes and Pigments
Mol File:
96-91-3.mol
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Picramic acid Chemical Properties

Melting point:
169°C
Boiling point:
336.62°C (rough estimate)
Density 
1.6937 (rough estimate)
vapor pressure 
0-0Pa at 25℃
refractive index 
1.6910 (estimate)
solubility 
Chloroform (Slightly), Water (Slightly)
form 
Solid
color 
Red to Dark Red
Water Solubility 
<0.1 g/100 mL at 20.5 ºC
Merck 
14,7409
Stability:
Stable. Combustible - burns rapidly: dangerous fire risk. Do not subject to shock, friction or heat. Incompatible with strong oxidizing agents.
LogP
0.93 at 25℃
CAS DataBase Reference
96-91-3(CAS DataBase Reference)
NIST Chemistry Reference
Picramic acid(96-91-3)
EPA Substance Registry System
Picramic acid (96-91-3)
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Safety Information

Hazard Codes 
E,Xn,F
Risk Statements 
1-20/21/22-52/53-11
Safety Statements 
35-61-36/37
RIDADR 
3317
RTECS 
SJ5800000
HazardClass 
4.1
PackingGroup 
II
Hazardous Substances Data
96-91-3(Hazardous Substances Data)

MSDS

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Picramic acid Usage And Synthesis

Chemical Properties

dark red crystals

Uses

manufacture of azo dyes; rarely as indicator (yellow with acids, red with alkalies); reagent for albumin.

General Description

Dark red needles or prisms. Red crystals. Water insoluble. Explosive in the dry state but desensitized by wetting. Easily ignited and once ignited burn readily.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Picramic acid should not be subjected to strong shock or heat, and is a dangerous fire risk. Picramic acid reacts with strong oxidizing agents. . Explodes if dried and exposed to heat, flame, friction or shock. Wetting greatly reduces this tendency. Treat as an explosive. Mixing with reducing agents, including hydrides, sulfides, nitrides, and alkali metals may lead to a vigorous reaction that culminates in a detonation. May explode in the presence of a base such as sodium hydroxide or potassium hydroxide, even in the presence of water or organic solvents. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. An amino acid (reacts as an acid with bases and as a base with acids).

Fire Hazard

Picramic acid ignites rapidly and burns relatively fast.

Flammability and Explosibility

Non flammable

Picramic acid Supplier

Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Email
market03@meryer.com
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Email
3bsc@sina.com
SelectLab Chemicals GmbH
Tel
+49-(0)2383-919350
Email
info@selectlab.de
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Email
sales@maya-r.com
Beijing HuaMeiHuLiBiological Chemical
Tel
010-56205725
Email
waley188@sohu.com