Picramic acid
Picramic acid Basic information
- Product Name:
- Picramic acid
- Synonyms:
-
- fourrine93
- Furro 4R
- furro4r
- Oxidation Base 21
- Phenol, 2-amino-4,6-dinitro-
- picramic
- Zoba 4R
- zoba4r
- CAS:
- 96-91-3
- MF:
- C6H5N3O5
- MW:
- 199.12
- EINECS:
- 202-544-6
- Product Categories:
-
- Intermediates of Dyes and Pigments
- Mol File:
- 96-91-3.mol
Picramic acid Chemical Properties
- Melting point:
- 169°C
- Boiling point:
- 336.62°C (rough estimate)
- Density
- 1.6937 (rough estimate)
- vapor pressure
- 0-0Pa at 25℃
- refractive index
- 1.6910 (estimate)
- solubility
- Chloroform (Slightly), Water (Slightly)
- form
- Solid
- color
- Red to Dark Red
- Water Solubility
- <0.1 g/100 mL at 20.5 ºC
- Merck
- 14,7409
- Stability:
- Stable. Combustible - burns rapidly: dangerous fire risk. Do not subject to shock, friction or heat. Incompatible with strong oxidizing agents.
- LogP
- 0.93 at 25℃
- CAS DataBase Reference
- 96-91-3(CAS DataBase Reference)
- NIST Chemistry Reference
- Picramic acid(96-91-3)
- EPA Substance Registry System
- Picramic acid (96-91-3)
Safety Information
- Hazard Codes
- E,Xn,F
- Risk Statements
- 1-20/21/22-52/53-11
- Safety Statements
- 35-61-36/37
- RIDADR
- 3317
- RTECS
- SJ5800000
- HazardClass
- 4.1
- PackingGroup
- II
- Hazardous Substances Data
- 96-91-3(Hazardous Substances Data)
MSDS
- Language:English Provider:6-Amino-2,4-dinitrophenol
Picramic acid Usage And Synthesis
Chemical Properties
dark red crystals
Uses
manufacture of azo dyes; rarely as indicator (yellow with acids, red with alkalies); reagent for albumin.
General Description
Dark red needles or prisms. Red crystals. Water insoluble. Explosive in the dry state but desensitized by wetting. Easily ignited and once ignited burn readily.
Air & Water Reactions
Highly flammable. Insoluble in water.
Reactivity Profile
Picramic acid should not be subjected to strong shock or heat, and is a dangerous fire risk. Picramic acid reacts with strong oxidizing agents. . Explodes if dried and exposed to heat, flame, friction or shock. Wetting greatly reduces this tendency. Treat as an explosive. Mixing with reducing agents, including hydrides, sulfides, nitrides, and alkali metals may lead to a vigorous reaction that culminates in a detonation. May explode in the presence of a base such as sodium hydroxide or potassium hydroxide, even in the presence of water or organic solvents. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. An amino acid (reacts as an acid with bases and as a base with acids).
Fire Hazard
Picramic acid ignites rapidly and burns relatively fast.
Flammability and Explosibility
Non flammable
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