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PALLADIUM(II) TRIFLUOROACETATE

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PALLADIUM(II) TRIFLUOROACETATE Basic information

Product Name:
PALLADIUM(II) TRIFLUOROACETATE
Synonyms:
  • Pd(CF3COO)2
  • Pd(TFA)2
  • Palladium(II) Trifluoroacetate (Pd(TFA)2)
  • adium(II) trifL
  • uoroacetate
  • Palladium(II) trifluoroacetate, 32% Pd
  • Palladium(II) trifluoroacetate Vetec(TM) reagent grade, 97%
  • Palladium(II) trifluoroacetate, 97% trace metals basis
CAS:
42196-31-6
MF:
C4F6O4Pd
MW:
332.45
Product Categories:
  • Pd
  • metal acetate salt
Mol File:
42196-31-6.mol
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PALLADIUM(II) TRIFLUOROACETATE Chemical Properties

Melting point:
~220 °C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Soluble in diethyl ether and acetone. Insoluble in benzene, chloroform and trifluoroacetic acid.
form 
Powder
color 
Brown
Sensitive 
Hygroscopic
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
InChIKey
WEJWWPJAIXRLIJ-UHFFFAOYSA-M
CAS DataBase Reference
42196-31-6(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
3-10
Hazard Note 
Irritant
TSCA 
No
HS Code 
28439000

MSDS

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PALLADIUM(II) TRIFLUOROACETATE Usage And Synthesis

Chemical Properties

tan to brown powder

Uses

Palladium(II) Trifluoroacetate is a pallaium salt of Trifluoroacetic Acid (T786035), a solvent used in a variety of organic synthesis and chemical processes. Also used in the synthesis of anticancer agents as well as phospholipase D inhibitors.

Uses

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Purification Methods

Suspend it in trifluoroacetic acid and evaporate it on a steam bath a couple of times. The residue is then dried in vacuum (40-80o) to give a brown powder. It is hygroscopic. [Stephenson et al. J Chem Soc 3632 1965, Trost & Metzner J Am Chem Soc 102 3572 1980.]

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