ChemicalBook > Product Catalog > Catalyst and Auxiliary > Fluorescent brightener > 4,4-Bis(diethylphosphonomethyl)biphenyl
4,4-Bis(diethylphosphonomethyl)biphenyl
4,4-Bis(diethylphosphonomethyl)biphenyl Basic information
- Product Name:
- 4,4-Bis(diethylphosphonomethyl)biphenyl
- Synonyms:
-
- Biphenyl-benzyl ester
- TETRAETHYL [4,4'-BIPHENYLYLENEBIS(METHYLENE)]BISPHOSPHONATE
- TETRAETHYL (4,4'-BIPHENYLYLENEDIMETHYLENE)DIPHOSPHONATE
- 4,4'-Bis(diethylphosphono methy)biphenyl
- [4,4'-Biphenylylenebis(methylene)]bisphosphonic Acid Tetraethyl Ester Tetraethyl [4,4'-Biphenylylenebis(methylene)]bisphosphonate
- [4,4'-BIPHENYLYLENEBIS(METHYLENE)]BISPHOSPHONIC ACID TETRAETHYL ESTER
- 4,4'-BIS[(DIETHOXYPHOSPHINYL)METHYL]BIPHENYL
- 4,4'-BIS(DIETHOXYPHOSPHOMETHYL)-1,1'-BIPHENYL
- CAS:
- 17919-34-5
- MF:
- C22H32O6P2
- MW:
- 454.43
- Product Categories:
-
- Synthetic Organic Chemistry
- Wittig & Horner-Emmons Reaction
- Biphenyl & Diphenyl ether
- Horner-Emmons Reaction
- Mol File:
- 17919-34-5.mol
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4,4-Bis(diethylphosphonomethyl)biphenyl Chemical Properties
- Melting point:
- 108-110°C
- Boiling point:
- 578.4±50.0 °C(Predicted)
- Density
- 1.155±0.06 g/cm3(Predicted)
- form
- powder to crystal
- color
- White to Almost white
- InChIKey
- DRCOGQJUVZRNSQ-UHFFFAOYSA-N
- CAS DataBase Reference
- 17919-34-5(CAS DataBase Reference)
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4,4-Bis(diethylphosphonomethyl)biphenyl Usage And Synthesis
Uses
4,4-Bis(diethylphosphonomethyl)biphenyl is a white powder used as an organic synthesis intermediate for the synthesis of fluorescent brighteners CBS-X, CBS-127, etc.
Synthesis
A mixture of 4,4’-bis(bromoethyl)biphenyl (0.204 g, 0.592 mmol) and P(OEt)3 (1 mL, 6.27mmol) was heated at 150°C for 12 h under N2. The mixture was purified over silica gel column chromatography using ethyl acetate as eluant, giving 258 mg of 4,4-Bis(diethylphosphonomethyl)biphenyl. Yield: 96 percent.
4,4-Bis(diethylphosphonomethyl)biphenylSupplier
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