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Benzyl 2-bromoethyl ether

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Benzyl 2-bromoethyl ether Basic information

Product Name:
Benzyl 2-bromoethyl ether
Synonyms:
  • BENZYL 2-BROMOETHYL ETHER
  • 1-BROMO-2-BENZYLOXYETHANE
  • 1-BENZYLOXY-2-BROMOETHANE
  • 2-BENZYLOXY-1-BROMOETHANE
  • Benzyl 2-bromoethyl ether, 97 % (GC)
  • (2-Bromoethoxymethyl)benzene
  • Benzyloxyethyl Bromide
  • Benzene, [(2-broMoethoxy)Methyl]-
CAS:
1462-37-9
MF:
C9H11BrO
MW:
215.09
EINECS:
629-202-2
Product Categories:
  • alkyl bromide
  • Building Blocks
  • C9
  • Chemical Synthesis
  • Organic Building Blocks
  • Oxygen Compounds
  • Protection & Derivatization Reagents (for Synthesis)
  • Synthetic Organic Chemistry
  • Ethers
  • Organic Building Blocks
  • Oxygen Compounds
  • 1462-37-9
Mol File:
1462-37-9.mol
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Benzyl 2-bromoethyl ether Chemical Properties

Boiling point:
254 °C(lit.)
Density 
1.36 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.541(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
form 
liquid
color 
colorless to yellow
Water Solubility 
Slightly soluble in water
InChI
InChI=1S/C9H11BrO/c10-6-7-11-8-9-4-2-1-3-5-9/h1-5H,6-8H2
InChIKey
FWOHDAGPWDEWIB-UHFFFAOYSA-N
SMILES
C1(COCCBr)=CC=CC=C1
CAS DataBase Reference
1462-37-9
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Safety Information

Hazard Codes 
Xn
Risk Statements 
22
Safety Statements 
24/25
RIDADR 
UN 3334
WGK Germany 
3
TSCA 
No
HS Code 
29093090

MSDS

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Benzyl 2-bromoethyl ether Usage And Synthesis

Chemical Properties

Clear colorless to pale yellow liquid

Uses

Benzyl 2-broMoethyl ether is a reactant used in the preparation of muscarinic antagonist.

Uses

Alkylation reagent for synthesis of a macrocyclic antifungal antibiotic. Building block used to prepare a copper phthalocyanine discotic liquid crystal.

General Description

Benzyl 2-bromoethyl ether is an organic building block. Its enthalpy of vaporization at boiling point (527.15K) has been reported to be 46.499kjoule/mol.

References

Martin W. M. Fijten.; Claudia Haensch.; Bart M. van Lankvelt.; Richard Hoogenboom.; Ulrich S. Schubert. Clickable Poly(2-Oxazoline)s as Versatile Building Blocks. Macromolecular Chemistry and Physics. 2008, 209 (18),1887-1895. DOI:10.1002/MACP.200800226
Britt A. Minch.; Wei Xia.; Carrie L. Donley.; Ryan M. Hernandez.; Chet Carter.; Michael D. Carducci.; Alice Dawson.; David F. O'Brien.; Neal R. Armstrong. Octakis(2-benzyloxyethylsulfanyl) Copper (II) Phthalocyanine: A New Liquid Crystalline Discotic Material with Benzyl-Terminated, Thioether-Linked Side Chains. Chem. Mater.2005,17 (7),1618-1627. DOI:10.1021/CM0483745
Org. Lett. 5, 4049-4052, (2003) 2. Chem. Mater. 17, 1618, (2005)

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