Basic information Reactions Safety Supplier Related

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT

Basic information Reactions Safety Supplier Related

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Basic information

Product Name:
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
Synonyms:
  • (S,R,R)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE
  • 3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine,dichloromethaneadduct,min.95%
  • (+)-N,N-Bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-amine, (11bS)
  • (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%
  • (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct
  • (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
  • (11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • (R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine
CAS:
415918-91-1
MF:
C36H30NO2P
MW:
539.61
Product Categories:
  • Chiral Phosphine
  • CPN
Mol File:
415918-91-1.mol
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(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Chemical Properties

Melting point:
102-103 °C
alpha 
+427° (c 0.83, CHCl3)
Boiling point:
710.7±63.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
pka
-0.57±0.20(Predicted)
color 
white
Sensitive 
moisture sensitive
CAS DataBase Reference
415918-91-1
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Safety Information

Hazard Codes 
Xn
Risk Statements 
36/37/38-22
Safety Statements 
26-36/37/39
WGK Germany 
3
HS Code 
2934.99.4400
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(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Usage And Synthesis

Reactions

  • A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins.
  • Ligand used in the iridium-catalyzed, enantioselective addition of nucleophiles to achiral
  • allylic esters.
  • Asymmetric hydrogenation.
  • Ir-catalyzed regio- and enantioselective Friedel-Crafts allylic alkylation of indoles.
  • Asymmetric hydrovinylation.
  • Used in 1,3-dipolar cycloaddition reactions of azomethine ylides and alkenes,9a and
  • Rh-catalyzed [5+2] cycloaddition of alkyne-vinyl-cyclopropanes.9b
  • Palladium-catalyzed enantioselective de-epimerization in catalytic asymmetric allylic alkylation.
  • Palladium-catalyzed enantioselective diamination of alkyl dienes.

Uses

(R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a'']dinaphthalen-4-yl)bis(1-phenylethyl)amine (CAS# 415918-91-1) is an organic catalyst used in the stereoselective preparation of homoallylic nitriles.

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCTSupplier

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(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT(415918-91-1)Related Product Information