1-Bromo-4-(trifluoromethoxy)benzene CAS#: 407-14-7

1-Bromo-4-(trifluoromethoxy)benzene Basic information

Product Name:

1-Bromo-4-(trifluoromethoxy)benzene

Synonyms:

4-BROMO-ALPHA,ALPHA,ALPHA-TRIFLUOROANISOLE
4-BROMO(TRIFLUOROMETHOXY)BENZENE
4-(TRIFLUOROMETHOXY)BROMOBENZENE
TIMTEC-BB SBB006606
P-TRIFLUOROMETHOXY BROMOBENZENE
P-BROMOTRIFLUOROMETHOXYBENZENE
Benzene, 1-bromo-4-(trifluoromethoxy)-
1-BROMO-4-(TRIFLUOROMETHOXY)BENZENE

CAS:

407-14-7

MF:

C7H4BrF3O

MW:

241.01

EINECS:

206-979-2

Product Categories:

Ethers
Organic Building Blocks
Trifluoromethoxybenzene Series
Fluorobenzene
Aromatic Halides (substituted)
Oxygen Compounds
Miscellaneous
Anisoles, Alkyloxy Compounds & Phenylacetates
Bromine Compounds
Fluorine Compounds
Building Blocks for Liquid Crystals
Chalcones, etc. (Building Blocks for Liquid Crystals)
Functional Materials
Pharmaceutical Intermediate
Trifluoroanisole series
alkyl bromide
bc0001

Mol File:

407-14-7.mol

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1-Bromo-4-(trifluoromethoxy)benzene Chemical Properties

Boiling point:: 80 °C50 mm Hg(lit.)
Density: 1.622 g/mL at 25 °C(lit.)
vapor pressure: 20 hPa (55 °C)
refractive index: n20/D 1.461(lit.)
Flash point:: 154 °F
storage temp.: Sealed in dry,Room Temperature
solubility: 11.7mg/l
form: Liquid
Specific Gravity: 1.64
color: Clear colorless to yellow
BRN: 2046332
InChI: InChI=1S/C7H4BrF3O/c8-5-1-3-6(4-2-5)12-7(9,10)11/h1-4H
InChIKey: SEAOBYFQWJFORM-UHFFFAOYSA-N
SMILES: C1(Br)=CC=C(OC(F)(F)F)C=C1
CAS DataBase Reference: 407-14-7(CAS DataBase Reference)
NIST Chemistry Reference: P-bromophenyl trifluoromethyl ether(407-14-7)

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Safety Information

Hazard Codes: Xn,N,Xi
Risk Statements: 22-36/37/38-43-51/53
Safety Statements: 26-36/37-61-37/39-36
RIDADR: UN 3082 9/PG 3
WGK Germany: 1
HazardClass: IRRITANT
HS Code: 29093090
Toxicity: LD50 orally in Rabbit: > 2500 mg/kg

MSDS

Language:English Provider:1-Bromo-4-(trifluoromethoxy)benzene
Language:English Provider:ACROS
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1-Bromo-4-(trifluoromethoxy)benzene Usage And Synthesis

Chemical Properties

CLEAR COLOURLESS TO YELLOW LIQUID

Uses

1-Bromo-4-(trifluoromethoxy)benzene was used in the synthesis of 4-{[4-[(2-ethylhexyloxy)-6-(4-morpholinylmethyl)-4-trifluoromethyl][1,1-biphenyl]-3-yl]methyl}morpholine.

Synthesis Reference(s)

Journal of the American Chemical Society, 109, p. 3708, 1987 DOI: 10.1021/ja00246a030

General Description

1-Bromo-4-(trifluoromethoxy)benzene on treatment with lithium diisopropylamide (LIDA) at -100°C gives 5-bromo-2-(trifluoromethoxy)phenyllithium and at -75°C it eliminates lithium bromide, thus generating 1,2-dehydro-4-(trifluoromethoxy)benzene.

1-Bromo-4-(trifluoromethoxy)benzene Preparation Products And Raw materials

Raw materials

Bromobenzene

1-Bromo-4-(trifluoromethoxy)benzeneSupplier

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