(R)-VAPOL
(R)-VAPOL Basic information
- Product Name:
- (R)-VAPOL
- Synonyms:
-
- (3R)-(-)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT
- (3S)-(+)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT
- (R)-VAPOL
- (S)-2,2'-DIPHENYL-(4-BIPHENANTHROL)
- (S)-VAPOL
- (R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL)
- (3S)-(+)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-dioldichloromethaneadduct,min.98%(S)-VAPOL
- (3S)-(+)-2,2''-DIPHENYL-[3,3''-BIPHENANTHRENE]-4,4''-DIOL DICHLOROMETHANE ADDUCT (S)-VAPOL
- CAS:
- 147702-15-6
- MF:
- C40H26O2
- MW:
- 538.63
- EINECS:
- 200-838-9
- Product Categories:
-
- BINOL Series
- Chiral Oxygen
- Mol File:
- 147702-15-6.mol
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(R)-VAPOL Chemical Properties
- Melting point:
- 185-191 °C
- alpha
- +125.0° (c 1.0, THF)
- Boiling point:
- 712.2±60.0 °C(Predicted)
- Density
- 1.286±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- form
- Powder
- pka
- 8.37±0.30(Predicted)
- color
- white to pale yellow
- optical activity
- [α]20/D 128°, c = 1 in chloroform
- InChIKey
- FXFOHEGGSYVOKR-UHFFFAOYSA-N
- CAS DataBase Reference
- 147702-15-6
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Safety Information
- Hazard Codes
- Xn
- Risk Statements
- 37/38-40-41
- Safety Statements
- 26-36/37/39-36/37-24/25-23
- WGK Germany
- 3
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(R)-VAPOL Usage And Synthesis
Reactions
- Chiral ligand in asymmetric autoinduction of Diels-Alder reactions.
- Chiral ligand used in catalytic asymmetric aziridination.
- Chiral ligand used in catalytic asymmetric imino aldol reaction.
- Chiral ligand used in catalytic asymmetric Petasis reaction.
Uses
VAPOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.
(R)-VAPOLSupplier
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