Basic information Safety Supplier Related
ChemicalBook >  Product Catalog >  Organic Chemistry >  Organometallic compounds >  Rare-Earth Metal >  EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE

EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE

Basic information Safety Supplier Related

EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE Basic information

Product Name:
EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE
Synonyms:
  • TFMC-EU
  • TRIS(TRIFLUOROMETHYLHYDROXYMETHYLENE-D-CAMPHORATO)EUROPIUM(III)
  • TRIS(3-TRIFLUOROACETYL-D-CAMPHORATO)EUROPIUM(III)
  • TRIS[3-(TRIFLUOROMETHYLHYDROXYMETHYLENE)-D-CAMPHORATO]EUROPIUM(III)
  • TRIS[3-(TRIFLUOROMETHYLHYDROXYMETHYLENE)-D-CAMPHORATO], EUROPIUM(III) DERIVATIVE
  • GDCL3:6H2O
  • EU(FACAM)3
  • Tris[3-(trifluoromethylhydroxymethylene)-D-camphorato], europium(III) derivative,95%
CAS:
34830-11-0
MF:
C36H42EuF9O6
MW:
893.68
EINECS:
252-232-9
Product Categories:
  • Chiral Shift ReagentsStable Isotopes
  • Asymmetric Synthesis
  • Chiral Resolution Reagents
  • NMR - Buffers and Reagents
  • NMR Solvents and Reagents
Mol File:
34830-11-0.mol
More
Less

EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE Chemical Properties

Melting point:
195-198 °C(lit.)
form 
solid
optical activity
[α]20/D +165°, c = 1% in chloroform (solvent is ethanol free)
Water Solubility 
Soluble in chloroform. Insoluble in water.
Sensitive 
Moisture Sensitive
InChI
1S/3C12H15F3O2.Eu/c3*1-10(2)6-4-5-11(10,3)8(16)7(6)9(17)12(13,14)15;/h3*6,17H,4-5H2,1-3H3;/q;;;+3/p-3/b3*9-7-;
InChIKey
BWIHMSGCCRUUCZ-NCJHBDPTSA-K
SMILES
CC1(C)C2CCC1(C)C(=O)\C2=C(/O[Eu](O\C(=C3\C4CCC(C)(C3=O)C4(C)C)C(F)(F)F)O\C(=C5\C6CCC(C)(C5=O)C6(C)C)C(F)(F)F)C(F)(F)F
CAS DataBase Reference
34830-11-0
EPA Substance Registry System
Europium, tris[1,7,7-trimethyl-3-(trifluoroacetyl-.kappa.O)bicyclo[2.2.1]heptan-2-onato-.kappa.O]- (34830-11-0)
More
Less

Safety Information

Safety Statements 
24/25
WGK Germany 
3
3-10
TSCA 
TSCA listed
Storage Class
11 - Combustible Solids

MSDS

More
Less

EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE Usage And Synthesis

Chemical Properties

yellow to orange powder

Uses

Optically active NMR shift reagent. Used with Ag(fod) for the enantiomeric resolution of sec-butylisothiouronium chloride. Also reactant involved in synthesis of europium acetyl camphorate phosphine oxide complexes and reactions with 1,10-N,N?-phenanthroline dioxide derivatives.

EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATESupplier

3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Email
3bsc@sina.com
Alfa Aesar
Tel
400-6106006
Email
saleschina@alfa-asia.com
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Shaanxi Dideu Medichem Co. Ltd
Tel
+86-029-89586680 +86-18192503167
Email
1026@dideu.com
Career Henan Chemica Co
Tel
+86-0371-86658258 +8613203830695
Email
laboratory@coreychem.com