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1,2-Dibromotetrachloroethane

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1,2-Dibromotetrachloroethane Basic information

Product Name:
1,2-Dibromotetrachloroethane
Synonyms:
  • 1,1,2,2-Tetrachloro-1,2-dibromoethane
  • 1,2-Dibromotetrachloroethane,97%
  • 1,2-DibroMotetrachloroethane, 97% 25GR
  • 1,2-DIBROMOTETRACHLOROETHANE FOR SYNTHES
  • 1,2-DibroMotetrachloroethane 97%
  • 1,2-dibromo-1,1,2,2-tetrachloro-ethan
  • 1,3-Dibromo-1,1,3,3-tetrachloro-propane
  • Dbtce
CAS:
630-25-1
MF:
C2Br2Cl4
MW:
325.64
EINECS:
211-136-7
Product Categories:
  • Ethanes/ethenes
  • Bromination
  • Halogenation
  • Synthetic Organic Chemistry
  • Alkyl
  • Halogenated Hydrocarbons
  • Organic Building Blocks
Mol File:
630-25-1.mol
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1,2-Dibromotetrachloroethane Chemical Properties

Melting point:
215-220 °C (dec.) (lit.)
Boiling point:
219℃
Density 
2.713 g/mL at 25 °C (lit.)
refractive index 
1.5100 (estimate)
Flash point:
105℃
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
Crystalline Powder, Crystals and/or Chunks
color 
White to beige
Water Solubility 
Insoluble in water.
BRN 
1699471
Stability:
Stable. Incompatible with strong oxidizing agents.
InChI
InChI=1S/C2Br2Cl4/c3-1(5,6)2(4,7)8
InChIKey
WJUKOGPNGRUXMG-UHFFFAOYSA-N
SMILES
C(Br)(Cl)(Cl)C(Br)(Cl)Cl
CAS DataBase Reference
630-25-1(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
RTECS 
KH9366000
HS Code 
29037800

MSDS

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1,2-Dibromotetrachloroethane Usage And Synthesis

Chemical Properties

colourless solid

Uses

1,2-dibromotetrachloroethane is used as a fire-proofing agent. It is actively involved in the conversion of sulfones to alkenes by Ramberg-Backlund rearrangement. It is an effective replacement for ozone depleting solvents like dibromodifluoromethane and tetrabromodifluoroethane. It is also utilized as a brominating reagent. In analytical chemistry, it is used in quantitative determination of perhalogenated compounds by high-performance liquid chromatography (HPLC).

General Description

1,2-Dibromotetrachloroethane acts as halogenating reagent for the one-pot conversion of sulfones to alkenes by Ramberg-B?cklund rearrangement. It is a useful brominating reagent for diaryl TeII species.

Synthesis

1,2-Dibromotetrachloroethane is prepared by reacting Tetrachloroethylene with Bromine refluxed for 2h.

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