Basic information Safety Supplier Related

(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL

Basic information Safety Supplier Related

(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL Basic information

Product Name:
(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL
Synonyms:
  • (R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL
  • (-)-DINOL
  • (4R-TRANS)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRA(2-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOL
  • (4R,5R)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRA(2-NAPHTHYL)DIOXOLANE-4,5-DIMETHANOL
  • (-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL
  • ((4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(di(naphthalen-2-yl)methanol)
  • (4R-trans)-2,2-di-me-A,A,A,A-tetra-2-nap -dioxo
  • (4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetra(2-naphthyl)dioxolane-4,5-di
CAS:
137365-09-4
MF:
C47H38O4
MW:
666.8
Mol File:
137365-09-4.mol
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(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL Chemical Properties

Melting point:
213-216 °C (lit.)
storage temp. 
2-8°C
optical activity
[α]20/D 116±2°, c = 1% in ethyl acetate
BRN 
6168481
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Safety Information

WGK Germany 
3
10

MSDS

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(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL Usage And Synthesis

Uses

(4R,5R)-2,2-Dimethyl-α,α,α'',α''-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol, is a privileged ligand analogue of TADDOLs. It can be broadly used in asymmetric synthesis. It is also shown that the titanium TADDOLate catalysts have broad application towards carbonyl addition and cycloaddition.

(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOLSupplier

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