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POTASSIUM 3-THIOPHENETRIFLUOROBORATE

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POTASSIUM 3-THIOPHENETRIFLUOROBORATE Basic information

Product Name:
POTASSIUM 3-THIOPHENETRIFLUOROBORATE
Synonyms:
  • potassium trifluoro(3-thiophenyl)boranuide
  • Potassium thiophen-3-yltrifluoroborate
  • Potassium trifluoro(thiophen-3-yl)borate
  • trifluoro(thiophen-3-yl)borate
  • potassium,trifluoro(thiophen-3-yl)boranuide
  • POTASSIUM 3-THIOPHENETRIFLUOROBORATE ISO 9001:2015 REACH
  • Borate(1-),trifluoro-3-thienyl-,potassium(1:1),(t-4)-
  • Potassium 3-thiophenetrifluoroborate
CAS:
192863-37-9
MF:
C4H3BF3S.K
MW:
190.04
Product Categories:
  • Boronic Acids and Derivatives
  • Heteroaryl
  • Trifluoroborate Salts
  • Molander Ates
  • Organoborons
Mol File:
192863-37-9.mol
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POTASSIUM 3-THIOPHENETRIFLUOROBORATE Chemical Properties

RTECS 
ED3367500
storage temp. 
Store under Nitrogen
form 
Powder
color 
White to off-white
CAS DataBase Reference
192863-37-9
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
2934999090
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POTASSIUM 3-THIOPHENETRIFLUOROBORATE Usage And Synthesis

Uses

Potassium 3-thiophenetrifluoroborate can be used as a reactant to prepare:

  • Methyl 3-amino-6-(thien-3-yl)thieno[3,2-b]pyridine-2-carboxylate by reacting with 6-bromothieno[3,2-b]pyridine.
  • Thiophene derivatives via Suzuki-Miyaura cross-coupling reaction with aryl halides using palladium complex as a catalyst.
  • 2-(Thiophen-3-yl)-3,1,2-benzoxazaborininone and 2-(thiophen-3-yl)-1,3,2-benzoxazaborininone by treating with 2-aminobenzoic acid and 2-hydroxybenzamide, respectively.

General Description

Potassium 3-thiophenetrifluoroborate is a nucleophilic boronated coupling reagent used to construct a C-C bond by reacting with aryl halides in the presence of a catalyst or under thermal conditions.

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