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Di-tert-amyl peroxide

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Di-tert-amyl peroxide Basic information

Product Name:
Di-tert-amyl peroxide
Synonyms:
  • Di-Tert-amyl peroxide (DTA-DTAP)
  • di-tert-pentyl-peroxid
  • Peroxide, bis(1,1-dimethylpropyl)
  • Peroxide, di-tert-pentyl-
  • Peroxide,bis(1,1-dimethylpropyl)
  • tert-Amyl peroxide
  • tert-Pentyl peroxide
  • DIAMYLPEROXIDE
CAS:
10508-09-5
MF:
C10H22O2
MW:
174.28
EINECS:
234-042-8
Mol File:
10508-09-5.mol
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Di-tert-amyl peroxide Chemical Properties

Melting point:
-55°C
Boiling point:
146 °C(lit.)
Density 
0.818 g/mL at 25 °C(lit.)
vapor pressure 
14.7hPa at 25℃
refractive index 
n20/D 1.409(lit.)
Flash point:
77 °F
Water Solubility 
13.83mg/L at 20℃
InChI
InChI=1S/C10H22O2/c1-7-9(3,4)11-12-10(5,6)8-2/h7-8H2,1-6H3
InChIKey
JJRDRFZYKKFYMO-UHFFFAOYSA-N
SMILES
O(C(C)(C)CC)OC(C)(C)CC
LogP
4.7 at 25℃
NIST Chemistry Reference
(CH3)2C(C2H5)OOC(CH3)2C2H5(10508-09-5)
EPA Substance Registry System
Peroxide, bis(1,1-dimethylpropyl) (10508-09-5)
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Safety Information

Hazard Codes 
O,Xn
Risk Statements 
8-22-38-7
Safety Statements 
7-16-17-36/37/39-47-14
RIDADR 
UN 3107 5.2
WGK Germany 
2
RTECS 
SD8300000
HazardClass 
5.2
PackingGroup 
II
HS Code 
29096000
Toxicity
mouse,LD50,oral,1450mg/kg (1450mg/kg),"Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 263, 1986.

MSDS

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Di-tert-amyl peroxide Usage And Synthesis

Description

Di-tert-amyl peroxide (DTAP) is a slightly yellowish, mobile liquid. This liquid dialkyl peroxide is used as an initiator (radical source) in the polymerisation of monomers, like e.g. ethylene, styrene, and (meth)acrylates.

Chemical Properties

Colorless to light yellow liquid

Uses

Di-tert-amyl peroxide is commonly used as a radical initiator to induce polymerisation (free radical polymerisation process) for the manufacture of plastic (polypropylene visbreaking, acrylicresins, LDPE/EVA), and as cross-linking agent for the production of resins (resin hardener). 

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