Basic information Safety Supplier Related

(+)-Bis[(R)-1-phenylethyl]amine

Basic information Safety Supplier Related

(+)-Bis[(R)-1-phenylethyl]amine Basic information

Product Name:
(+)-Bis[(R)-1-phenylethyl]amine
Synonyms:
  • (+)-Bis[(R)-1-phenylethyl]amine, ChiPros
  • [R-(R*,R*)]-(+)-Bis(α-methylbenzyl)amine
  • (+)-Bis[(R)-1-phenylethyl]amine
  • (+)-Bis[(R)-1-phenylethyl]aMine, ChiPros|r, 99%, ee 98+%
  • (R)-bis((R)-1-phenylethyl)aMine
  • (+)-Bis[(R)-1-phenylethyl]amine 99%
  • (+)-BIS (R)-1-PHENYLETHYL!AMINE HYDRO-
  • (+)-Bis[(R)-1-phenylethyl]amine, 99% (99+% EE/GLC)
CAS:
23294-41-9
MF:
C16H19N
MW:
225.34
Mol File:
23294-41-9.mol
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(+)-Bis[(R)-1-phenylethyl]amine Chemical Properties

Melting point:
~260 °C
Boiling point:
86 °C0.05 mm Hg(lit.)
alpha 
199 º (NEAT)
Density 
0.985 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.5523(lit.)
Flash point:
>230 °F
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
pka
8.79±0.29(Predicted)
optical activity
[α]20/D +199.0°, neat
Water Solubility 
Insoluble in water.
BRN 
3590931
CAS DataBase Reference
23294-41-9
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37
WGK Germany 
3
3
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(+)-Bis[(R)-1-phenylethyl]amine Usage And Synthesis

Uses

(+)-Bis[(R)-1-phenylethyl]amine play a very extensive role of making chirally optically active drugs and compounds. Also as intermediates.

Uses

(+)-Bis[(R)-1-phenylethyl]amine can be used:

  • In the synthesis of?β-amino acids.
  • In the preparation of chiral C(19)-C(26) and C(27)-C(32) moieties of scytophycin C.
  • To induce enantioselectivity in the deprotonation of prochiral ketones.
  • As a starting material for the synthesis of chiral phenolate ligands through Mannich condensation reaction.
  • In the synthesis of chiral phosphoramidite ligands.
  • To prepare chiral cyclic isoimidium salts, which are further used to synthesize chiral lactones through Diels-Alder reaction.

(+)-Bis[(R)-1-phenylethyl]amineSupplier

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