Phenylsilane
Phenylsilane Basic information
- Product Name:
- Phenylsilane
- Synonyms:
-
- Phenylsilane, 98% 25ML
- Phenylsilane, 98% 5ML
- Phenylsilane,98%
- Phenylsilane≥ 98% (GC)
- PHENYLSILANE
- Benzene, silyl-
- Fenylsilan
- phenyl-silan
- CAS:
- 694-53-1
- MF:
- C6H8Si
- MW:
- 108.21
- EINECS:
- 211-772-5
- Product Categories:
-
- Silane compounds
- Reduction
- Si (Classes of Silicon Compounds)
- Si-H Compounds
- Synthetic Organic Chemistry
- Organometallic Reagents
- Organosilicon
- Others
- Mol File:
- 694-53-1.mol
Phenylsilane Chemical Properties
- Melting point:
- -64 to -68°C
- Boiling point:
- 120 °C (lit.)
- Density
- 0.877 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.510(lit.)
- Flash point:
- 45 °F
- storage temp.
- Flammables area
- form
- clear liquid
- color
- Colorless to Almost colorless
- Specific Gravity
- 0.868
- Water Solubility
- Contact with water releases a flammable alcohol. Soluble in water (Contact with water releases flammable gases), and most common organic solvents.
- Sensitive
- Air & Moisture Sensitive
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- BRN
- 2935169
- InChIKey
- PARWUHTVGZSQPD-UHFFFAOYSA-N
- CAS DataBase Reference
- 694-53-1(CAS DataBase Reference)
- EPA Substance Registry System
- Silane, phenyl- (694-53-1)
Safety Information
- Hazard Codes
- F,Xn
- Risk Statements
- 11-14/15-20/22-36/37/38
- Safety Statements
- 16-43
- RIDADR
- UN 3399 4.3/PG 2
- WGK Germany
- 1
- RTECS
- VV4825000
- F
- 10-21
- TSCA
- Yes
- HazardClass
- 4.3
- PackingGroup
- II
- HS Code
- 29319090
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
Phenylsilane Usage And Synthesis
Chemical Properties
clear colorless liquid
Uses
Phenylsilane (PhSiH3) may be used as a reducing agent for the partial reduction of phosphine oxide groups in poly(4,4′-diphenylphenylphosphine oxide) (PAPO) to phosphine. It can also undergo photopolymerization with methyl methacrylate(MMA) to form poly(MMA) containing SiH groups. PhSiH3 may be used as a silicon source to synthesize crystalline Si nanowires via Au-nanocrystal-seeded supercritical fluid-liquid-solid (SFLS) synthesis.
Uses
phenylsilane is used as a pharmaceutical intermediate.
Application
Employed in the reduction of esters to ethers. Reduces α,β-unsaturated ketones to saturated ketones in the presence of tri-n-butyltin hydride. Reduces tin amides to tin hydrides. Used in the tin-catalyzed reduction of nitroalkanes to alkanes. Reduces α-halo ketones in presence of Mo(0).
Definition
ChEBI: Phenylsilane is an organosilicon compound that is benzene in which a hydrogen is replaced by a silyl group. It has a role as a reducing agent. It is an organosilicon compound and a member of benzenes.
Phenylsilane Preparation Products And Raw materials
Raw materials
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Phenylsilane(694-53-1)Related Product Information
- Phenyltriethoxysilane
- Phenyltrichlorosilane
- TRIS(TRIMETHYLSILOXY)PHENYLSILANE 99%,TRIS(TRIMETHYLSILOXY)PHENYLSILANE,M3T(Ph):tris(trimethylsiloxy)phenylsilan
- PHENYLSELENENYL CHLORIDE
- Trimethoxyphenylsilane
- PHENYLTHIOACETONITRILE
- Dichloromethylphenylsilane
- Chlorodimethylphenylsilane
- DIMETHYL(PENTAFLUOROPHENYL)SILANE
- tert-Butylchlorodiphenylsilane
- Triphenylsilyl chloride
- Dimethoxymethylphenylsilane
- Chlorodimethylpentafluorophenylsilane
- Octaphenylcyclotetrasiloxane
- Diphenylsilane
- DIPHENYLMETHYLSILANE
- Triphenylsilane
- Diphenylsilanediol