Basic information Precautions for Use Safety Supplier Related
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Cyhalofop-butyl

Basic information Precautions for Use Safety Supplier Related

Cyhalofop-butyl Basic information

Product Name:
Cyhalofop-butyl
Synonyms:
  • (R)-butyl 2-(4-(4-cyano-2-fluorophenoxy)phenoxy)propanoate
  • cyhalofop butyl ester
  • XDE 537
  • Propanoic acid, 2-4-(4-cyano-2-fluorophenoxy)phenoxy-, butyl ester, (2R)-
  • cyhalofop-butyl (pa iso, ansi)
  • (2R)-2-(4-(4-Cyano-2-fluorophenoxy)phenoxy)propanoic acid butyl ester
  • Butyl-(R)-2-[4-(4-cyano-2-fluorophenoxy) phenoxy]propionate
  • CYHALOFOP-BUTYL
CAS:
122008-85-9
MF:
C20H20FNO4
MW:
357.38
Mol File:
122008-85-9.mol
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Cyhalofop-butyl Chemical Properties

Melting point:
47.0 to 51.0 °C
Boiling point:
449.1±45.0 °C(Predicted)
Density 
1.21±0.1 g/cm3(Predicted)
Flash point:
122℃
storage temp. 
Sealed in dry,2-8°C
solubility 
soluble in Methanol
form 
Solid
color 
White to Almost white
InChIKey
TYIYMOAHACZAMQ-CQSZACIVSA-N
LogP
4.400 (est)
CAS DataBase Reference
122008-85-9(CAS DataBase Reference)
EPA Substance Registry System
Cyhalofop-butyl (122008-85-9)
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Safety Information

Hazard Codes 
Xn,N
Risk Statements 
22-50
Safety Statements 
61
RIDADR 
UN 3077 9 / PGIII
WGK Germany 
3
HazardClass 
9
PackingGroup 
III
HS Code 
29269090
Hazardous Substances Data
122008-85-9(Hazardous Substances Data)
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Cyhalofop-butyl Usage And Synthesis

Precautions for Use

Cyhalofop-butyl does not present any useful pre-emergence activity. It can be applied from germination to the four-leafstage of barnyard grass with granular formulations, and from germination to the six-leaf stage with liquid formulations. lt israinfast within 2-3 hours and has no residual activity. The US product label states that 2.3 L/ha of crop oil concentrateshould be added to the tank for all treatments. The product poses low risk to nearby crops such as cotton, soybeans andvegetables but Dow advises that drift to more sensitive crops such as maize, nectarines, peaches, sugar cane and sorghum should be avoided.

Description

Cyhalofop-butyl is a post-emergence, aryloxyphenoxypropionate herbicide, which is used in controlling weeds in rice plantations. Its mode of action involves the inhibition of acetyl-coenzyme A carboxylase (ACCase) biosynthesis.
Cyhalofop-butyl has a low aqueous solubility and is non-volatile. It is non expected to be eprsistent in soil systems but may be persistent in some water systems depending on local conditions. Cyhalofop-butyl is moderately toxic to fish and aquatic plants but has a low toxicity ti aquatic invertebrates, birds and honeybees. It has a low mammalian oral toxicity.

Uses

Cyhalofop-butyl may be used as a reference standard in the determination of cyhalofop-butyl in rice samples using liquid chromatography coupled with diode array detector (LC-DAD).

Definition

ChEBI: Cyhalofop-butyl is an aromatic ether.

Trade name

Clincher (Technical)
Clincher (CA)
Clincher (SF)
U.S. Producer: Dow AgroSciences LLC

Mode of action

Cyhalofop-butyl is an inhibitor of acetyl coenzyme -A carboxylase, a pivotal enzyme in plant fatty acid biosynthesis.

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