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2,5-Dibromothiophene

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2,5-Dibromothiophene Basic information

Product Name:
2,5-Dibromothiophene
Synonyms:
  • Thiophene,2,5-dibromo-
  • 2,5-DIBROMO THIOPHENE 98.0%MIN
  • TH-2Bra
  • 2,5-Dibromthiophen
  • 2,5-DibroMothiophene, 95% 25GR
  • 2,5-Dibromothiophene,95%
  • alpha,alpha-Dibromothiophene
  • NSC 4488
CAS:
3141-27-3
MF:
C4H2Br2S
MW:
241.93
EINECS:
221-547-3
Product Categories:
  • Sulphur Derivatives
  • Thiophene&Benzothiophene
  • Thiophenes
  • Metal Isotopes
  • Thiophens
  • Sulfur & Selenium Compounds
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • ThiophenesBuilding Blocks
  • Heterocycle-oher series
  • bc0001
Mol File:
3141-27-3.mol
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2,5-Dibromothiophene Chemical Properties

Melting point:
-6 °C (lit.)
Boiling point:
211 °C (lit.)
Density 
2.147 g/mL at 25 °C (lit.)
refractive index 
1.627-1.63
Flash point:
99 °C
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform, Methanol
form 
Liquid
color 
Clear pale yellow to brown
Specific Gravity
2.147
Water Solubility 
practically insoluble
BRN 
109899
InChIKey
KBVDUUXRXJTAJC-UHFFFAOYSA-N
CAS DataBase Reference
3141-27-3(CAS DataBase Reference)
NIST Chemistry Reference
Thiophene, 2,5-dibromo-(3141-27-3)
EPA Substance Registry System
Thiophene, 2,5-dibromo- (3141-27-3)
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Safety Information

Hazard Codes 
T+,Xi
Risk Statements 
68-43-36/37/38-28-20/21
Safety Statements 
45-36/37/39-28A-26-36
RIDADR 
UN2810
WGK Germany 
3
Hazard Note 
Irritant
TSCA 
T
HazardClass 
6.1
PackingGroup 
II
HS Code 
29349990

MSDS

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2,5-Dibromothiophene Usage And Synthesis

Chemical Properties

Light Yellow Liquid

Uses

2,5-Dibromothiophene, is mainly used as pharmaceutical intermediate and synthesis intermediate.

Uses

2,5-Dibromothiophene was used as starting reagent for the synthesis of α,α′-didecylquater-, -quinque- and -sexi-thiophenes. It was used in the preparation of soluble α,ω-diformyl-a-oligothiophenes.

Synthesis Reference(s)

The Journal of Organic Chemistry, 58, p. 3072, 1993 DOI: 10.1021/jo00063a028
Synthesis, p. 890, 1988 DOI: 10.1055/s-1988-27740

General Description

2,5-Dibromothiophene polymerizes by debromination with magnesium catalyzed by nickel compounds to form poly(2,5- thienylene) .

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