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ChemicalBook >  Product Catalog >  Chemical Reagents >  Organic reagents >  Phosphine ligand >  (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE

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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE Basic information

Product Name:
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE
Synonyms:
  • MANDYPHOS SL-M004-1
  • (aR,aR)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis[bis(4-methoxy-3,5
  • (S,S)-(-)-2,2'-Bis((R)-(N,N-dimethylamino)-(phenyl)methyl)-1,1'-di(bis(3,5-dimethyl-4-methoxyphenyl)phosphino)ferrocene
  • (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocene,min.97%
  • (r,r)-1,1'-bis[(r)-α-(dimethylamino)phenylmethyl]-2,2'-bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocene (acc to cas)
  • (αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-2,2'-bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocene
  • (SP,SμP)-1,1μ-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2μ-bis[(R)-α-(dimethylamino)benzyl]ferrocene
  • Mandyphos SL-M004-1, (1R,1μR)- 1,1μ-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2μ-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS)
CAS:
494227-37-1
MF:
C64H74FeN2O4P210*
MW:
1053.08
Product Categories:
  • Chiral Phosphine
  • Ferrocene Series
  • Mandyphos Series
Mol File:
494227-37-1.mol
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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE Chemical Properties

alpha 
-61.5° (c 1.0, CHCl3)
form 
solid
color 
yellow to orange-red
Stability:
store cold
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Safety Information

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
HS Code 
29319090
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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE Usage And Synthesis

Chemical Properties

Orange powder

Uses

It may be used as a chiral ligand in the rhodium complex-catalyzed hydrogenation reaction, a key step during the synthesis of argatroban.

General Description

Mandyphos SL-M004-1 is a chiral ferrocenyl based diphosphine ligand belonging to the Mandyphos family.

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENESupplier

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