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4-Fluoronitrobenzene

Basic information Uses Safety Supplier Related

4-Fluoronitrobenzene Basic information

Product Name:
4-Fluoronitrobenzene
Synonyms:
  • 4-Fluornitrobenzol
  • 4-fluoro-1-nitrobenzene
  • Benzene,1-fluoro-4-nitro-
  • For fluoronitrobenzene
  • NSC 10281
  • p-fluoronitrobenzene anion
  • Fluoronitrobenzene3
  • Fluoronitrobenzenecolorlesssolid
CAS:
350-46-9
MF:
C6H4FNO2
MW:
141.1
EINECS:
206-502-8
Product Categories:
  • Phenyls & Phenyl-Het
  • Nitro Compounds
  • Aromatic Halides (substituted)
  • Halides
  • Nitrogen Compounds
  • Organic Building Blocks
  • Phenyls & Phenyl-Het
Mol File:
350-46-9.mol
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4-Fluoronitrobenzene Chemical Properties

Melting point:
21 °C (lit.)
Boiling point:
205 °C (lit.)
Density 
1.33 g/mL at 25 °C (lit.)
vapor density 
>1 (vs air)
vapor pressure 
5.5 mm Hg ( 70 °C)
refractive index 
n20/D 1.531(lit.)
Flash point:
182 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Liquid After Melting
Specific Gravity
1.330
color 
deep greenish-yellow
Water Solubility 
Insoluble in water.
BRN 
606923
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey
WFQDTOYDVUWQMS-UHFFFAOYSA-N
LogP
1.8 at 20℃
CAS DataBase Reference
350-46-9(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-fluoro-4-nitro-(350-46-9)
EPA Substance Registry System
p-Fluoronitrobenzene (350-46-9)
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Safety Information

Hazard Codes 
Xn,T,Xi
Risk Statements 
20/21/22-33
Safety Statements 
36-36/37
RIDADR 
UN 2811 6.1/PG 3
WGK Germany 
1
RTECS 
DA1400000
Hazard Note 
Toxic/Irritant
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29049085
Hazardous Substances Data
350-46-9(Hazardous Substances Data)

MSDS

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4-Fluoronitrobenzene Usage And Synthesis

Uses

4-Nitrofluorobenzene, is an aryl fluorinated building block, and a common intermediate used for the synthesis of many industrial useful compounds. It is used for the preparation of novel soluble aromatic polyimides, such as 1,3,5-Tris(4-aminophenoxy)benzene (TAB).

Chemical Properties

yellow liquid

Uses

1-Fluoro-4-nitrobenzene used as a component of hair dyes, as pharmaceutical intermediates. It is also used for the preparation of novel soluble aromatic polyimides

Synthesis Reference(s)

Journal of the American Chemical Society, 78, p. 6034, 1956 DOI: 10.1021/ja01604a022
Tetrahedron, 52, p. 23, 1996 DOI: 10.1016/0040-4020(95)00867-8
Tetrahedron Letters, 30, p. 7199, 1989 DOI: 10.1016/S0040-4039(01)93933-4

Flammability and Explosibility

Non flammable

Purification Methods

Crystallise it from EtOH. [Beilstein 5 H 241, 5 IV 719.]

4-FluoronitrobenzeneSupplier

Qi-Chem Co., Ltd. Gold
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