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Methyl 4-bromo-3-methylbenzoate

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Methyl 4-bromo-3-methylbenzoate Basic information

Product Name:
Methyl 4-bromo-3-methylbenzoate
Synonyms:
  • METHYL 4-BROMO-3-METHYLBENZOATE
  • METHYL 4-BROMO-M-TOLUATE
  • Methyl 4-bromo-3-met
  • 2-Bromo-5-(methoxycarbonyl)toluene
  • 4-Bromo-m-toluic Acid Methyl Ester 4-Bromo-3-methylbenzoic Acid Methyl Ester Methyl 4-Bromo-m-toluate
  • 2-Bromo-5-(methoxycarbonyl)toluene, Methyl 4-bromo-m-toluate
  • Methyl 4-Bromo-3-Methoxynicotinate
  • Methyl 4-broMo-3-Methylbenzoate, 97%, 97%
CAS:
148547-19-7
MF:
C9H9BrO2
MW:
229.07
EINECS:
629-103-4
Product Categories:
  • blocks
  • Bromides
  • Carboxes
  • Aromatic Esters
  • Benzene series
  • Benzoic acid
  • Acids & Esters
  • Bromine Compounds
  • C8 to C9
  • Carbonyl Compounds
  • Esters
  • Pyridines
  • bc0001
Mol File:
148547-19-7.mol
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Methyl 4-bromo-3-methylbenzoate Chemical Properties

Melting point:
38-44 °C (lit.)
Boiling point:
287.4±20.0 °C(Predicted)
Density 
1.433±0.06 g/cm3(Predicted)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
soluble in Methanol
form 
Low Melting Solid or Liquid
color 
White to yellow
BRN 
6593534
CAS DataBase Reference
148547-19-7(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29163990

MSDS

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Methyl 4-bromo-3-methylbenzoate Usage And Synthesis

Chemical Properties

Colorless low melting solid

Uses

Methyl 4-bromo-3-methylbenzoate may be used in the preparation of:

  • 4-bromo-3-vinylbenzoic acid
  • 4-bromo-3-(methylphenyl)methanol
  • methyl (E)-4-bromo-3-[(phenylmethoxyimino)methyl]benzoate

It may be used as a starting material in the total synthesis of (-)-martinellic acid.

General Description

Methyl 4-bromo-3-methylbenzoate, an aromatic ester, undergoes Suzuki coupling with 2-chloroboronic acid to afford the corresponding biaryl.

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