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4-NITROCINNAMALDEHYDE

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4-NITROCINNAMALDEHYDE Basic information

Product Name:
4-NITROCINNAMALDEHYDE
Synonyms:
  • 4-NITROCINNAMALDEHYDE
  • 3-(4-NITROPHENYL)-2-PROPENAL
  • PARA-NITROCINNAMALDEHYDE
  • p-Nitrocinnamaldehyde,98%
  • 4-Nitrobenzeneacrylaldehyde
  • 4-Nitrobenzenepropenal
  • 3-(4-Nitrophenyl)acrylaldehyde 3-(4-Nitrophenyl)-2-propenal
  • 3-(4-Nitrophenyl)acrylaldehyde
CAS:
1734-79-8
MF:
C9H7NO3
MW:
177.16
EINECS:
217-076-8
Product Categories:
  • Aromatic Aldehydes & Derivatives (substituted)
Mol File:
1734-79-8.mol
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4-NITROCINNAMALDEHYDE Chemical Properties

Melting point:
140-143 °C(lit.)
Boiling point:
309.06°C (rough estimate)
Density 
1.3312 (rough estimate)
refractive index 
1.5200 (estimate)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
Water Solubility 
Insoluble in water.
Sensitive 
Air Sensitive
BRN 
1565424
CAS DataBase Reference
1734-79-8(CAS DataBase Reference)
EPA Substance Registry System
2-Propenal, 3-(4-nitrophenyl)- (1734-79-8)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/38
Safety Statements 
26-36
WGK Germany 
3
RTECS 
GD6650000
TSCA 
Yes
HS Code 
29130000

MSDS

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4-NITROCINNAMALDEHYDE Usage And Synthesis

Chemical Properties

beige to yellow-brown crystals or cryst. powder

Uses

Doebner-Miller reaction the 4- nitrocinnamaldehyde and 2-methylaniline in concentrated HC1 give the corresponding 8-methyl-2-phenylquinoline (3: R = 4'-N02) directly. The asymmetric Friedel-Crafts-type alkylation in aqueous media reaction of 4-Nitrocinnamaldehydr with N-methyl indole using trifluoroacetic acid (TFA) salt of the PEG-PS-supported prolyl peptide having the polyleucine tether as a catalyst. 4-Nitrocinnamaldehyde has been used in the preparation of 2, 2?-[(E)-3-(4-nitrophenyl) prop-2-ene-1,1-diyl] bis(3-hydroxy-5, 5-dimethylcyclohex-2-en-1-one).

4-NITROCINNAMALDEHYDESupplier

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