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3,3',4,4'-Biphenyltetracarboxylic dianhydride

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3,3',4,4'-Biphenyltetracarboxylic dianhydride Basic information

Product Name:
3,3',4,4'-Biphenyltetracarboxylic dianhydride
Synonyms:
  • 3,3',4,4'-Biphenyl tetracarboxylic diandhydride
  • [1,1'-Biphenyl]-3,3',4,4'-tetracarboxylic3,4:3',4'-dianhydride
  • 3,4,3',4'-Biphenyltetracarboxylic acid dianhydride
  • 3,3',4,4'-Biphenyltetracarboxylic dianhydride 97%
  • 4,4'-Biphthalic Anhydride (purified by sublimation)
  • 3,3'4,4'-Biphenyl tetracarboxylic acid dianhydride(s-BPDA)
  • S-BDPA
  • S-BPDA
CAS:
2420-87-3
MF:
C16H6O6
MW:
294.22
EINECS:
219-342-9
Product Categories:
  • fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, monomer for polyimide film, pharmaceutical intermediates
  • fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials
  • Anhydride Monomers
  • Polymer Science
  • API
  • strong recommend
  • Biphenyl & Diphenyl ether
  • Aromatic Tetracarboxylic Dianhydrides (for High-Performance Polymer Research)
  • Biphenyls (for High-Performance Polymer Research)
  • Functional Materials
  • Reagent for High-Performance Polymer Research
  • Monomer for Polyimide film
  • Monomers
  • 1
  • 2420-87-3
  • OLED
Mol File:
2420-87-3.mol
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3,3',4,4'-Biphenyltetracarboxylic dianhydride Chemical Properties

Melting point:
299-305 °C (lit.)
Boiling point:
614.9±48.0 °C(Predicted)
Density 
1.625±0.06 g/cm3(Predicted)
vapor pressure 
0Pa at 20℃
storage temp. 
Inert atmosphere,Room Temperature
solubility 
almost transparency in hot DMF
form 
powder to crystal
color 
Off-white
λmax
300nm(lit.)
InChI
InChI=1S/C16H6O6/c17-13-9-3-1-7(5-11(9)15(19)21-13)8-2-4-10-12(6-8)16(20)22-14(10)18/h1-6H
InChIKey
WKDNYTOXBCRNPV-UHFFFAOYSA-N
SMILES
C1(=O)C2=C(C=C(C3C=CC4C(=O)OC(=O)C=4C=3)C=C2)C(=O)O1
LogP
3.91
CAS DataBase Reference
2420-87-3(CAS DataBase Reference)
NIST Chemistry Reference
3,3',4,4'-Biphenyltetracarboxylic acid dianhydride(2420-87-3)
EPA Substance Registry System
[5,5'-Biisobenzofuran]-1,1',3,3'-tetrone (2420-87-3)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29173990
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3,3',4,4'-Biphenyltetracarboxylic dianhydride Usage And Synthesis

Chemical Properties

BPDA (3,3',4,4'-Biphenyltetracarboxylic dianhydride) is a raw material for the polyimide resin component of one of the super-engineering plastics. It is used for many important information and electronic technology products such as mobile phones and copying machines.

Uses

3,3',4,4'-biphenyltetracarboxylic dianhydride be used for the preparation of a polyimide material.

Uses

s-BPDA can be used in the synthesis of high molecular weight aromatic polyamide fibers. It can also be used in the formation of hybrid nanocomposite films.

Preparation

The preparation of 3,3',4,4'-Biphenyltetracarboxylic dianhydride is as follows:In a nitrogen atmosphere, add N-(3-N,N-dimethylamino-propyl)-4-chlorophthalimide (26.65g, 0.1moL),Zinc powder (3.25g, 0.05moL), anhydrous NiCl2 (127.5mg, 1mmoL),Triphenylphosphine (250mg, 1mmoL) and 70 mL of anhydrous DMAc were stirred at 50°C for 24 hours, and 55mL of solvent DMAc was recovered under reduced pressure. Add 80g of xylene to the system and reflux (recrystallize), filter out the inorganic matter, the clarified filtrate will be cooled and precipitated, filtered, and vacuum dried for 10 hours. 21.8g of 3,3',4,4'-biphenylbisimine was obtained with a yield of 94%. In a 100mL reaction flask, add 4.62g (0.01mol) of the above 3,3',4,4'-biphenylbisimine and 9g of 20% sodium hydroxide aqueous solution, and heat to reflux for 24 hours. Filter and adjust pH=1 with concentrated hydrochloric acid to obtain 3,3’,4,4’-biphenyltetracarboxylic acid. After filtering, wash with water three times and reflux with water with 20mL trimethylbenzene.2.85g of white 3,3′,4,4′-biphenyltetracarboxylic dianhydride was obtained, the yield was 97%.

Application

3,3′,4,4′-biphenyltetracarboxylic dianhydride (BPDA) and 3,3′- and 4,4′-diaminodiphenylsulfones enable to prepare homo- and copolyimides. 3,3',4,4'-Biphenyltetracarboxylic dianhydride is commonly employed to synthesized the aromatic polyimide fibers which is one member of high performance fibers with high strength, high modulus, high and low temperature resistance, and radiation resistance. BPDA could be used to synthesize a series of hyper-cross-linked polymers (HPB-s) with waste polystyrene (WPS) foam. HPB-s has promising potential in purifying dye wastewater[1-2].

General Description

3,3′,4,4′-Biphenyltetracarboxylic dianhydride (s-BPDA) is a rigid symmetric polyamide with a diamine having a long distance between amine groups and reactive endgaps.

Flammability and Explosibility

Non flammable

Advantages

1.Excellent thermal stability
2.Good chemical resistance
3.Stable mechanical properties
4.Polyimide does not require the addition of flame retardants to prevent combustion.

References

[1] Zhao M, et al. Porous Adsorbents Cross-Linked with Waste Polystyrene Foam and 3,3′,4,4′-Biphenyltetracarboxylic Acid Dianhydride for the Effective Removal and Enrichment of Cationic Dyes. ACS Applied Polymer Materials, 2023.
[2] Zhang Q, et al. Morphology of polyimide fibers derived from 3,3′,4,4′-biphenyltetracarboxylic dianhydride and 4,4′-oxydianiline. Journal of Applied Polymer Science, 2004; 93: 669-675.

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